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Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II)

The title compound, [Cd(C9H10NS2)2(C5H5N)], features a five-coordinate CdII atom, being coordinated by two nearly symmetrically chelating di­thio­carbamate ligands and a pyridine N atom. The resulting NS4 donor set defines a distorted coordination geometry tending toward square pyramidal. In the mol...

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Main Authors: Ehsan, Muhammad Ali, Muhammad Mazhar,, Tiekink, Edward R. T. *
Format: Article
Language:English
Published: International Union of Crystallography 2016
Subjects:
QD Chemistry
Online Access:http://eprints.sunway.edu.my/660/1/IUCrData%202016%201%20x152429.pdf
http://eprints.sunway.edu.my/660/
http://dx.doi.org/10.1107/S2414314615024293
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spelling my.sunway.eprints.6602020-10-07T09:56:11Z http://eprints.sunway.edu.my/660/ Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II) Ehsan, Muhammad Ali Muhammad Mazhar, Tiekink, Edward R. T. * QD Chemistry The title compound, [Cd(C9H10NS2)2(C5H5N)], features a five-coordinate CdII atom, being coordinated by two nearly symmetrically chelating di­thio­carbamate ligands and a pyridine N atom. The resulting NS4 donor set defines a distorted coordination geometry tending toward square pyramidal. In the mol­ecular packing, centrosymmetric ten-membered {...HCNCS}2 synthons arise as a result of methyl­ene-C-H...S inter­actions. These are connected into layers parallel to (10-2) via weak methyl-C-H...[pi](phen­yl) inter­actions. International Union of Crystallography 2016 Article PeerReviewed text en cc_by_nc_nd http://eprints.sunway.edu.my/660/1/IUCrData%202016%201%20x152429.pdf Ehsan, Muhammad Ali and Muhammad Mazhar, and Tiekink, Edward R. T. * (2016) Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II). IUCrData, 1 (1). x152429. ISSN 2414-3146 http://dx.doi.org/10.1107/S2414314615024293 doi:10.1107/S2414314615024293
institution Sunway University
building Sunway Campus Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Sunway University
content_source Sunway Institutional Repository
url_provider http://eprints.sunway.edu.my/
language English
topic QD Chemistry
spellingShingle QD Chemistry
Ehsan, Muhammad Ali
Muhammad Mazhar,
Tiekink, Edward R. T. *
Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II)
description The title compound, [Cd(C9H10NS2)2(C5H5N)], features a five-coordinate CdII atom, being coordinated by two nearly symmetrically chelating di­thio­carbamate ligands and a pyridine N atom. The resulting NS4 donor set defines a distorted coordination geometry tending toward square pyramidal. In the mol­ecular packing, centrosymmetric ten-membered {...HCNCS}2 synthons arise as a result of methyl­ene-C-H...S inter­actions. These are connected into layers parallel to (10-2) via weak methyl-C-H...[pi](phen­yl) inter­actions.
format Article
author Ehsan, Muhammad Ali
Muhammad Mazhar,
Tiekink, Edward R. T. *
author_facet Ehsan, Muhammad Ali
Muhammad Mazhar,
Tiekink, Edward R. T. *
author_sort Ehsan, Muhammad Ali
title Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II)
title_short Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II)
title_full Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II)
title_fullStr Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II)
title_full_unstemmed Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II)
title_sort bis(n-benzyl-n-methyldithiocarbamato-κ2s,s′)(pyridine-κn)cadmium(ii)
publisher International Union of Crystallography
publishDate 2016
url http://eprints.sunway.edu.my/660/1/IUCrData%202016%201%20x152429.pdf
http://eprints.sunway.edu.my/660/
http://dx.doi.org/10.1107/S2414314615024293
_version_ 1680323391454707712
score 13.15806

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