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Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II)

The title compound, [Cd(C9H10NS2)2(C5H5N)], features a five-coordinate CdII atom, being coordinated by two nearly symmetrically chelating di­thio­carbamate ligands and a pyridine N atom. The resulting NS4 donor set defines a distorted coordination geometry tending toward square pyramidal. In the mol...

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Bibliographic Details
Main Authors: Ehsan, Muhammad Ali, Muhammad Mazhar,, Tiekink, Edward R. T. *
Format: Article
Language:English
Published: International Union of Crystallography 2016
Subjects:
QD Chemistry
Online Access:http://eprints.sunway.edu.my/660/1/IUCrData%202016%201%20x152429.pdf
http://eprints.sunway.edu.my/660/
http://dx.doi.org/10.1107/S2414314615024293
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Summary:The title compound, [Cd(C9H10NS2)2(C5H5N)], features a five-coordinate CdII atom, being coordinated by two nearly symmetrically chelating di­thio­carbamate ligands and a pyridine N atom. The resulting NS4 donor set defines a distorted coordination geometry tending toward square pyramidal. In the mol­ecular packing, centrosymmetric ten-membered {...HCNCS}2 synthons arise as a result of methyl­ene-C-H...S inter­actions. These are connected into layers parallel to (10-2) via weak methyl-C-H...[pi](phen­yl) inter­actions.

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