Bis[bis(N-2-hydroxyethyl,N-isopropyl-dithiocarbamato)mercury(II)]2: crystal structure and Hirshfeld surface analysis

The presence of both κ2-chelating and μ2,κ2-tridentate bridging dithiocarbamate ligands in centrosymmetric {Hg[S2CN(iPr)CH2CH2OH]2}2 (1) leads to globular aggregates that are linked into a three-dimensional architecture via hydroxyl-O–H···O(hydroxy) hydrogen bonding. The structure contrasts that of...

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Main Authors: Jotani, Mukesh M., Tan, Yee Seng *, Tiekink, Edward R. T. *
Format: Article
Language:English
Published: De Gruyter 2016
Subjects:
Online Access:http://eprints.sunway.edu.my/658/1/Z.%20Kristallogr.%202016%20231%20403.pdf
http://eprints.sunway.edu.my/658/
http://dx.doi.org/10.1515/zkri-2016-1943
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spelling my.sunway.eprints.6582020-10-07T09:49:46Z http://eprints.sunway.edu.my/658/ Bis[bis(N-2-hydroxyethyl,N-isopropyl-dithiocarbamato)mercury(II)]2: crystal structure and Hirshfeld surface analysis Jotani, Mukesh M. Tan, Yee Seng * Tiekink, Edward R. T. * QD Chemistry The presence of both κ2-chelating and μ2,κ2-tridentate bridging dithiocarbamate ligands in centrosymmetric {Hg[S2CN(iPr)CH2CH2OH]2}2 (1) leads to globular aggregates that are linked into a three-dimensional architecture via hydroxyl-O–H···O(hydroxy) hydrogen bonding. The structure contrasts that of Hg[S2CN(CH2CH2OH)2]2 (2; this is a literature structure) in which square planar units are connected into supramolecular chains via Hg···S secondary bonding; chains are connected in the crystal structure by hydroxyl-O–H···O(hydroxy) hydrogen bonding. A Hirshfeld surface analysis on 1 and 2 reveal the influence of O–H···O and Hg···S interactions on the molecular packing as well as the distinctive interactions, such as C–H···S interactions in 1 and C–H···π (HgS2C) contacts in 2. A bibliographic survey shows the different structural motifs observed for 1 and 2 are complimented by an additional five motifs for binary mercury(II) dithiocarbamates revealing a fascinating structural diversity for this class of compound. De Gruyter 2016-07 Article PeerReviewed text en http://eprints.sunway.edu.my/658/1/Z.%20Kristallogr.%202016%20231%20403.pdf Jotani, Mukesh M. and Tan, Yee Seng * and Tiekink, Edward R. T. * (2016) Bis[bis(N-2-hydroxyethyl,N-isopropyl-dithiocarbamato)mercury(II)]2: crystal structure and Hirshfeld surface analysis. Zeitschrift für Kristallographie - Crystalline Materials, 231 (7). pp. 403-413. ISSN 2194-4946 http://dx.doi.org/10.1515/zkri-2016-1943 doi:10.1515/zkri-2016-1943
institution Sunway University
building Sunway Campus Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Sunway University
content_source Sunway Institutional Repository
url_provider http://eprints.sunway.edu.my/
language English
topic QD Chemistry
spellingShingle QD Chemistry
Jotani, Mukesh M.
Tan, Yee Seng *
Tiekink, Edward R. T. *
Bis[bis(N-2-hydroxyethyl,N-isopropyl-dithiocarbamato)mercury(II)]2: crystal structure and Hirshfeld surface analysis
description The presence of both κ2-chelating and μ2,κ2-tridentate bridging dithiocarbamate ligands in centrosymmetric {Hg[S2CN(iPr)CH2CH2OH]2}2 (1) leads to globular aggregates that are linked into a three-dimensional architecture via hydroxyl-O–H···O(hydroxy) hydrogen bonding. The structure contrasts that of Hg[S2CN(CH2CH2OH)2]2 (2; this is a literature structure) in which square planar units are connected into supramolecular chains via Hg···S secondary bonding; chains are connected in the crystal structure by hydroxyl-O–H···O(hydroxy) hydrogen bonding. A Hirshfeld surface analysis on 1 and 2 reveal the influence of O–H···O and Hg···S interactions on the molecular packing as well as the distinctive interactions, such as C–H···S interactions in 1 and C–H···π (HgS2C) contacts in 2. A bibliographic survey shows the different structural motifs observed for 1 and 2 are complimented by an additional five motifs for binary mercury(II) dithiocarbamates revealing a fascinating structural diversity for this class of compound.
format Article
author Jotani, Mukesh M.
Tan, Yee Seng *
Tiekink, Edward R. T. *
author_facet Jotani, Mukesh M.
Tan, Yee Seng *
Tiekink, Edward R. T. *
author_sort Jotani, Mukesh M.
title Bis[bis(N-2-hydroxyethyl,N-isopropyl-dithiocarbamato)mercury(II)]2: crystal structure and Hirshfeld surface analysis
title_short Bis[bis(N-2-hydroxyethyl,N-isopropyl-dithiocarbamato)mercury(II)]2: crystal structure and Hirshfeld surface analysis
title_full Bis[bis(N-2-hydroxyethyl,N-isopropyl-dithiocarbamato)mercury(II)]2: crystal structure and Hirshfeld surface analysis
title_fullStr Bis[bis(N-2-hydroxyethyl,N-isopropyl-dithiocarbamato)mercury(II)]2: crystal structure and Hirshfeld surface analysis
title_full_unstemmed Bis[bis(N-2-hydroxyethyl,N-isopropyl-dithiocarbamato)mercury(II)]2: crystal structure and Hirshfeld surface analysis
title_sort bis[bis(n-2-hydroxyethyl,n-isopropyl-dithiocarbamato)mercury(ii)]2: crystal structure and hirshfeld surface analysis
publisher De Gruyter
publishDate 2016
url http://eprints.sunway.edu.my/658/1/Z.%20Kristallogr.%202016%20231%20403.pdf
http://eprints.sunway.edu.my/658/
http://dx.doi.org/10.1515/zkri-2016-1943
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