Homoleptic [ONO]2Ti(IV) type complexes of amino-acid-tethered phenolato, Schiff-base ligands: Synthesis, characterization, time-resolved fluorescence spectroscopy, and cytotoxicity against ovarian and colon cancer cells

• Main Authors: Shpilt, Zohar, Manne, Rajesh, Rahman, M. A., Mitra, Sivaprasad, Tiekink, Edward R. T. *, Baul, T. S. B., Tshuva, E. Y.
• Format: Article
• Language: English
• Published: Wiley 2019
• Subjects: QD Chemistry
• Online Access: http://eprints.sunway.edu.my/1229/1/Tiekink%20AOC%202020%2034%20e5309.pdf; http://eprints.sunway.edu.my/1229/; https://doi.org/10.1002/aoc.5309

Six homoleptic Ti(IV) compounds of dianionic tridentate Schiff base ligands were synthesized from chiral amino acids, 2-hydroxybenzaldehyde and Ti(OiPr)4. The compounds were spectroscopically characterized and the molecular geometries were established by X-ray crystallography. The ligands coordinat...