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A one-pot synthesis of N2,6-diaryl-5,6-dihydro-1,3,5-triazine-2,4-diamines and systematic evaluation of their ability to host ethanol in crystals

A convenient one-pot method for the preparation of N2 ,6-diaryl-5,6-dihydro-1,3,5-triazine-2,4-diamines was developed using a three-component synthesis of 1,6-diaryl-1,6-dihydro-1,3,5-triazine-2,4-diamines followed by their Dimroth rearrangement to the desired products. The prepared compounds crys...

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Main Authors: Ahmad Junaid,, Tan, Yee Seng *, Tiekink, Edward R. T. *, Dolzhenko, Anton V
Format: Article
Language:English
Published: Royal Society of Chemistry 2019
Subjects:
QD Chemistry
Online Access:http://eprints.sunway.edu.my/1126/1/Tiekink%20A%20one%20pot%20synthesis%20RSC%20Adv%202019%209%2037660.pdf
http://eprints.sunway.edu.my/1126/
http://doi.org/10.1039/c9ra08795h
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spelling my.sunway.eprints.11262020-10-07T07:55:56Z http://eprints.sunway.edu.my/1126/ A one-pot synthesis of N2,6-diaryl-5,6-dihydro-1,3,5-triazine-2,4-diamines and systematic evaluation of their ability to host ethanol in crystals Ahmad Junaid, Tan, Yee Seng * Tiekink, Edward R. T. * Dolzhenko, Anton V QD Chemistry A convenient one-pot method for the preparation of N2 ,6-diaryl-5,6-dihydro-1,3,5-triazine-2,4-diamines was developed using a three-component synthesis of 1,6-diaryl-1,6-dihydro-1,3,5-triazine-2,4-diamines followed by their Dimroth rearrangement to the desired products. The prepared compounds crystallized from ethanol as ethanol clathrates (1 : 1). X-ray crystallography on several products confirmed the adoption of 5,6-dihydro-tautomer. The thermal analysis and powder X-ray diffraction experiments on selected compounds suggested that thermal desolvation of crystals was irreversible. Royal Society of Chemistry 2019-11-13 Article PeerReviewed text en cc_by_nc_nd_4 http://eprints.sunway.edu.my/1126/1/Tiekink%20A%20one%20pot%20synthesis%20RSC%20Adv%202019%209%2037660.pdf Ahmad Junaid, and Tan, Yee Seng * and Tiekink, Edward R. T. * and Dolzhenko, Anton V (2019) A one-pot synthesis of N2,6-diaryl-5,6-dihydro-1,3,5-triazine-2,4-diamines and systematic evaluation of their ability to host ethanol in crystals. RSC Advances, 9 (64). pp. 37660-37667. ISSN 2046-2069 (In Press) http://doi.org/10.1039/c9ra08795h doi:10.1039/c9ra08795h
institution Sunway University
building Sunway Campus Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Sunway University
content_source Sunway Institutional Repository
url_provider http://eprints.sunway.edu.my/
language English
topic QD Chemistry
spellingShingle QD Chemistry
Ahmad Junaid,
Tan, Yee Seng *
Tiekink, Edward R. T. *
Dolzhenko, Anton V
A one-pot synthesis of N2,6-diaryl-5,6-dihydro-1,3,5-triazine-2,4-diamines and systematic evaluation of their ability to host ethanol in crystals
description A convenient one-pot method for the preparation of N2 ,6-diaryl-5,6-dihydro-1,3,5-triazine-2,4-diamines was developed using a three-component synthesis of 1,6-diaryl-1,6-dihydro-1,3,5-triazine-2,4-diamines followed by their Dimroth rearrangement to the desired products. The prepared compounds crystallized from ethanol as ethanol clathrates (1 : 1). X-ray crystallography on several products confirmed the adoption of 5,6-dihydro-tautomer. The thermal analysis and powder X-ray diffraction experiments on selected compounds suggested that thermal desolvation of crystals was irreversible.
format Article
author Ahmad Junaid,
Tan, Yee Seng *
Tiekink, Edward R. T. *
Dolzhenko, Anton V
author_facet Ahmad Junaid,
Tan, Yee Seng *
Tiekink, Edward R. T. *
Dolzhenko, Anton V
author_sort Ahmad Junaid,
title A one-pot synthesis of N2,6-diaryl-5,6-dihydro-1,3,5-triazine-2,4-diamines and systematic evaluation of their ability to host ethanol in crystals
title_short A one-pot synthesis of N2,6-diaryl-5,6-dihydro-1,3,5-triazine-2,4-diamines and systematic evaluation of their ability to host ethanol in crystals
title_full A one-pot synthesis of N2,6-diaryl-5,6-dihydro-1,3,5-triazine-2,4-diamines and systematic evaluation of their ability to host ethanol in crystals
title_fullStr A one-pot synthesis of N2,6-diaryl-5,6-dihydro-1,3,5-triazine-2,4-diamines and systematic evaluation of their ability to host ethanol in crystals
title_full_unstemmed A one-pot synthesis of N2,6-diaryl-5,6-dihydro-1,3,5-triazine-2,4-diamines and systematic evaluation of their ability to host ethanol in crystals
title_sort one-pot synthesis of n2,6-diaryl-5,6-dihydro-1,3,5-triazine-2,4-diamines and systematic evaluation of their ability to host ethanol in crystals
publisher Royal Society of Chemistry
publishDate 2019
url http://eprints.sunway.edu.my/1126/1/Tiekink%20A%20one%20pot%20synthesis%20RSC%20Adv%202019%209%2037660.pdf
http://eprints.sunway.edu.my/1126/
http://doi.org/10.1039/c9ra08795h
_version_ 1680323411790790656
score 13.15806

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