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Statistical Optimization of the Fenton Process for Treatment of Amoxicillin and Cloxacillin Antibiotic Aqueous Solution by Response Surface Methodology

Fenton treatment of amoxicillin and cloxacillin antibiotic aqueous solution was optimized using the central composite design (CCD) and response surface methodology (RSM). The optimum operating conditions which achieved 78.98, 72.96 and 81.18% removal of COD, TOC and NH3-N, respectively at pH 3...

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Main Authors: Affam, A. C., Chaudhuri, M., Kutty, S. R. M.
Format: Book Section
Published: Universiti Teknologi PETRONAS 2012
Subjects:
TD Environmental technology. Sanitary engineering
Online Access:http://eprints.utp.edu.my/9803/1/1569547873.pdf
http://eprints.utp.edu.my/9803/
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spelling my.utp.eprints.98032017-01-19T08:21:52Z Statistical Optimization of the Fenton Process for Treatment of Amoxicillin and Cloxacillin Antibiotic Aqueous Solution by Response Surface Methodology Affam, A. C. Chaudhuri, M. Kutty, S. R. M. TD Environmental technology. Sanitary engineering Fenton treatment of amoxicillin and cloxacillin antibiotic aqueous solution was optimized using the central composite design (CCD) and response surface methodology (RSM). The optimum operating conditions which achieved 78.98, 72.96 and 81.18% removal of COD, TOC and NH3-N, respectively at pH 3 were H2O2/COD molar ratio 2.0, H2O2/Fe2+ molar ratio 76 and reaction time 90 min. Removal efficiency by model prediction and experimental validation were in close agreement (<0.4% error). Biodegradability (BOD5/COD ratio) improved from zero to 0.33, indicating that the treated antibiotic aqueous solution was amenable to biological treatment. FTIR spectra indicated degradation of the beta-lactam bond of the antibiotics. Universiti Teknologi PETRONAS 2012 Book Section PeerReviewed application/pdf http://eprints.utp.edu.my/9803/1/1569547873.pdf Affam, A. C. and Chaudhuri, M. and Kutty, S. R. M. (2012) Statistical Optimization of the Fenton Process for Treatment of Amoxicillin and Cloxacillin Antibiotic Aqueous Solution by Response Surface Methodology. In: Proceedings 2012 International Conference on Civil, Offshore and Environmental Engineering. Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750 Tronoh, Perak, Malaysia. ISBN 978-983-2271-77-2 http://eprints.utp.edu.my/9803/
institution Universiti Teknologi Petronas
building UTP Resource Centre
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Petronas
content_source UTP Institutional Repository
url_provider http://eprints.utp.edu.my/
topic TD Environmental technology. Sanitary engineering
spellingShingle TD Environmental technology. Sanitary engineering
Affam, A. C.
Chaudhuri, M.
Kutty, S. R. M.
Statistical Optimization of the Fenton Process for Treatment of Amoxicillin and Cloxacillin Antibiotic Aqueous Solution by Response Surface Methodology
description Fenton treatment of amoxicillin and cloxacillin antibiotic aqueous solution was optimized using the central composite design (CCD) and response surface methodology (RSM). The optimum operating conditions which achieved 78.98, 72.96 and 81.18% removal of COD, TOC and NH3-N, respectively at pH 3 were H2O2/COD molar ratio 2.0, H2O2/Fe2+ molar ratio 76 and reaction time 90 min. Removal efficiency by model prediction and experimental validation were in close agreement (<0.4% error). Biodegradability (BOD5/COD ratio) improved from zero to 0.33, indicating that the treated antibiotic aqueous solution was amenable to biological treatment. FTIR spectra indicated degradation of the beta-lactam bond of the antibiotics.
format Book Section
author Affam, A. C.
Chaudhuri, M.
Kutty, S. R. M.
author_facet Affam, A. C.
Chaudhuri, M.
Kutty, S. R. M.
author_sort Affam, A. C.
title Statistical Optimization of the Fenton Process for Treatment of Amoxicillin and Cloxacillin Antibiotic Aqueous Solution by Response Surface Methodology
title_short Statistical Optimization of the Fenton Process for Treatment of Amoxicillin and Cloxacillin Antibiotic Aqueous Solution by Response Surface Methodology
title_full Statistical Optimization of the Fenton Process for Treatment of Amoxicillin and Cloxacillin Antibiotic Aqueous Solution by Response Surface Methodology
title_fullStr Statistical Optimization of the Fenton Process for Treatment of Amoxicillin and Cloxacillin Antibiotic Aqueous Solution by Response Surface Methodology
title_full_unstemmed Statistical Optimization of the Fenton Process for Treatment of Amoxicillin and Cloxacillin Antibiotic Aqueous Solution by Response Surface Methodology
title_sort statistical optimization of the fenton process for treatment of amoxicillin and cloxacillin antibiotic aqueous solution by response surface methodology
publisher Universiti Teknologi PETRONAS
publishDate 2012
url http://eprints.utp.edu.my/9803/1/1569547873.pdf
http://eprints.utp.edu.my/9803/
_version_ 1738655791966060544
score 13.154949

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