Adsorptive Removal of Chromium(VI) from Aqueous Solution by an Agricultural Waste-Based Activated Carbon

Activated carbon was prepared from an agricultural waste, coconut coir, and its characteristics were compared with that of a commercial bituminous coal-based activated carbon. The activated carbon possessed higher surface area, micropore area, micropore volume and average pore diameter, and we...

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Bibliographic Details
Main Authors: Chaudhuri, M., Azizan, N. K. B.
Format: Article
Published: Springer 2012
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Online Access:http://eprints.utp.edu.my/7685/1/home%3FSGWID%3D0-0-1003-0-0%26aqId%3D2040854%26download%3D1%26checkval%3D8cd732f3cc58f45bf5fed8370af3a552
http://www.springer.com/home?SGWID=0-0-1003-0-0&aqId=2040854&download=1&checkval=8cd732f3cc58f45bf5fed8370af3a552
http://eprints.utp.edu.my/7685/
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Summary:Activated carbon was prepared from an agricultural waste, coconut coir, and its characteristics were compared with that of a commercial bituminous coal-based activated carbon. The activated carbon possessed higher surface area, micropore area, micropore volume and average pore diameter, and well-developed meso- and micropores. Batch test on adsorption of chromium(VI) by the coconut coir activated carbon showed that the extent of chromium(VI) adsorption was dependent on chromium(VI) concentration, contact time, pH and activated carbon dose. Maximum adsorption occurred at pH 1.0–2.0 and equilibrium adsorption was attained in 2.5 h. Chromium(VI) adsorption followed pseudo second-order kinetics. Equilibrium chromium(VI) adsorption data for the coconut coir activated carbon and the commercial activated carbon were described by the Langmuir and Freundlich isotherm models and indicated higher chromium(VI) adsorption capacity of the coconut coir activated carbon. Chromium(VI) adsorption capacity of the coconut coir activated carbon was compared with that of activated carbon prepared from different waste material and bituminous coal.