LiVOPO4 as a new cathode materials for Li-ion rechargeable battery

mprovement in the rate properties of orthorhombic LiVOPO4 was investigated and it was found that making a fine powder of LiVOPO4by the mechanical milling pretreatment is effective for increasing the de-intercalation capacity of Li from LiVOPO4. The electrochemical de-intercalation capacity at high c...

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Bibliographic Details
Main Authors: Bustam, Mohamad Azmi, Ishihara, Tatsumi, Nishiguchi, Hiroyasu, Takita, Yusaku
Format: Citation Index Journal
Published: Elsevier B.V. 2005
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Online Access:http://eprints.utp.edu.my/3802/1/Azmi_2005_Journal-of-Power-Sources.pdf
http://eprints.utp.edu.my/3802/
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Summary:mprovement in the rate properties of orthorhombic LiVOPO4 was investigated and it was found that making a fine powder of LiVOPO4by the mechanical milling pretreatment is effective for increasing the de-intercalation capacity of Li from LiVOPO4. The electrochemical de-intercalation capacity at high current density can further increase by optimizing the acetylene black amount as a conducting binder. Theoptimized acetylene black amount was 15 wt.% and intercalation capacity of Li was achieved a value of 100 and 60 mAh g−1 at high rate condition of C/5 (0.4mAcm−2) and 1C (2mAcm−2), respectively.