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Hydration behavior study of imidazolium based ILs in water

These ILs were chosen to provide an understanding of the influence of the cation alkyl chain length, and the anion influence on the volumetric properties. Densities for aqueous solutions of ionic liquids having 1-butyl-3-methylimidazolium as cation and chloride, bromide, iodide and acetate as anions...

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Main Author: Lal, B.
Format: Article
Published: Trans Tech Publications Ltd 2014
Online Access:https://www.scopus.com/inward/record.uri?eid=2-s2.0-84914164286&doi=10.4028%2fwww.scientific.net%2fAMM.625.553&partnerID=40&md5=757839d1123a8690d4e3f67ac72e36aa
http://eprints.utp.edu.my/31898/
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spelling my.utp.eprints.318982022-03-29T03:39:28Z Hydration behavior study of imidazolium based ILs in water Lal, B. These ILs were chosen to provide an understanding of the influence of the cation alkyl chain length, and the anion influence on the volumetric properties. Densities for aqueous solutions of ionic liquids having 1-butyl-3-methylimidazolium as cation and chloride, bromide, iodide and acetate as anions were accurately measured at various concentrations and temperature, (288.15, 293.15, 298.15, 303.15 and 308.15) K. The results have been discussed in terms of hydrophobic hydration, hydrophobic interactions, and water structural changes in aqueous medium. The data were used in evaluating thermodynamic properties as apparent molar volumes, and apparent molar expansions. Apparent molar volumes were found to increase with temperature. © 2014 Trans Tech Publications, Switzerland. Trans Tech Publications Ltd 2014 Article NonPeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-84914164286&doi=10.4028%2fwww.scientific.net%2fAMM.625.553&partnerID=40&md5=757839d1123a8690d4e3f67ac72e36aa Lal, B. (2014) Hydration behavior study of imidazolium based ILs in water. Applied Mechanics and Materials, 625 . pp. 553-556. http://eprints.utp.edu.my/31898/
institution Universiti Teknologi Petronas
building UTP Resource Centre
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Petronas
content_source UTP Institutional Repository
url_provider http://eprints.utp.edu.my/
description These ILs were chosen to provide an understanding of the influence of the cation alkyl chain length, and the anion influence on the volumetric properties. Densities for aqueous solutions of ionic liquids having 1-butyl-3-methylimidazolium as cation and chloride, bromide, iodide and acetate as anions were accurately measured at various concentrations and temperature, (288.15, 293.15, 298.15, 303.15 and 308.15) K. The results have been discussed in terms of hydrophobic hydration, hydrophobic interactions, and water structural changes in aqueous medium. The data were used in evaluating thermodynamic properties as apparent molar volumes, and apparent molar expansions. Apparent molar volumes were found to increase with temperature. © 2014 Trans Tech Publications, Switzerland.
format Article
author Lal, B.
spellingShingle Lal, B.
Hydration behavior study of imidazolium based ILs in water
author_facet Lal, B.
author_sort Lal, B.
title Hydration behavior study of imidazolium based ILs in water
title_short Hydration behavior study of imidazolium based ILs in water
title_full Hydration behavior study of imidazolium based ILs in water
title_fullStr Hydration behavior study of imidazolium based ILs in water
title_full_unstemmed Hydration behavior study of imidazolium based ILs in water
title_sort hydration behavior study of imidazolium based ils in water
publisher Trans Tech Publications Ltd
publishDate 2014
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-84914164286&doi=10.4028%2fwww.scientific.net%2fAMM.625.553&partnerID=40&md5=757839d1123a8690d4e3f67ac72e36aa
http://eprints.utp.edu.my/31898/
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score 13.209306

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