Performance enhancement of mixed matrix membranes through the incorporation of alkanolamines for CO2/CH4 separation
Diethanolamine (DEA) solution was used in this study to enhance the performance of polyethersulfone (PES) � carbon molecular sieve (CMS) mixed matrix membrane (MMMs). These new amine mixed matrix membranes (A3Ms) were fabricated at room temperature by using fixed concentration of PES, CMS and diff...
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Gadjah Mada University
2014
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my.utp.eprints.317872022-03-29T03:37:24Z Performance enhancement of mixed matrix membranes through the incorporation of alkanolamines for CO2/CH4 separation Nasir, R. Mukhtar, H. Man, Z. Bt. Shaharun, M.S. Abu Bakar, M.Z. Diethanolamine (DEA) solution was used in this study to enhance the performance of polyethersulfone (PES) � carbon molecular sieve (CMS) mixed matrix membrane (MMMs). These new amine mixed matrix membranes (A3Ms) were fabricated at room temperature by using fixed concentration of PES, CMS and different concentrations (5, 10 wt. ) of DEA. The developed mixed matrix membranes were characterized by using field emission scanning electron microscope (FESEM) and thermogravimetric analyser (TGA) in order to investigate the effect of DEA addition on morphology and thermal stability. Gas performance tests were also performed to measure the permeance and selectivity. The characterization results showed that the membranes were thermally stable, dense and non-porous. The gas performance tests showed that the permeance and selectivity of A3Ms is higher than the native PES membrane. CO2 permeance increases with the increase of DEA concentration. Hence it was found that with an addition of 10 (wt. ) DEA at a pressure of 2 bars, the CO2 permeance was increased from 50.86 to 127.06 GPU and the CO2/CH4 selectivity was also increased from 3.08 to 12.30. © 2015 Gadjah Mada University. All rights reserved. Gadjah Mada University 2014 Article NonPeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-84925362413&doi=10.22146%2fajche.49706&partnerID=40&md5=39ef9a29defe307a4809c740e1cbe48b Nasir, R. and Mukhtar, H. and Man, Z. and Bt. Shaharun, M.S. and Abu Bakar, M.Z. (2014) Performance enhancement of mixed matrix membranes through the incorporation of alkanolamines for CO2/CH4 separation. ASEAN Journal of Chemical Engineering, 14 (2). pp. 28-37. http://eprints.utp.edu.my/31787/ |
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Diethanolamine (DEA) solution was used in this study to enhance the performance of polyethersulfone (PES) � carbon molecular sieve (CMS) mixed matrix membrane (MMMs). These new amine mixed matrix membranes (A3Ms) were fabricated at room temperature by using fixed concentration of PES, CMS and different concentrations (5, 10 wt. ) of DEA. The developed mixed matrix membranes were characterized by using field emission scanning electron microscope (FESEM) and thermogravimetric analyser (TGA) in order to investigate the effect of DEA addition on morphology and thermal stability. Gas performance tests were also performed to measure the permeance and selectivity. The characterization results showed that the membranes were thermally stable, dense and non-porous. The gas performance tests showed that the permeance and selectivity of A3Ms is higher than the native PES membrane. CO2 permeance increases with the increase of DEA concentration. Hence it was found that with an addition of 10 (wt. ) DEA at a pressure of 2 bars, the CO2 permeance was increased from 50.86 to 127.06 GPU and the CO2/CH4 selectivity was also increased from 3.08 to 12.30. © 2015 Gadjah Mada University. All rights reserved. |
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Nasir, R. Mukhtar, H. Man, Z. Bt. Shaharun, M.S. Abu Bakar, M.Z. |
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Nasir, R. Mukhtar, H. Man, Z. Bt. Shaharun, M.S. Abu Bakar, M.Z. Performance enhancement of mixed matrix membranes through the incorporation of alkanolamines for CO2/CH4 separation |
author_facet |
Nasir, R. Mukhtar, H. Man, Z. Bt. Shaharun, M.S. Abu Bakar, M.Z. |
author_sort |
Nasir, R. |
title |
Performance enhancement of mixed matrix membranes through the incorporation of alkanolamines for CO2/CH4 separation |
title_short |
Performance enhancement of mixed matrix membranes through the incorporation of alkanolamines for CO2/CH4 separation |
title_full |
Performance enhancement of mixed matrix membranes through the incorporation of alkanolamines for CO2/CH4 separation |
title_fullStr |
Performance enhancement of mixed matrix membranes through the incorporation of alkanolamines for CO2/CH4 separation |
title_full_unstemmed |
Performance enhancement of mixed matrix membranes through the incorporation of alkanolamines for CO2/CH4 separation |
title_sort |
performance enhancement of mixed matrix membranes through the incorporation of alkanolamines for co2/ch4 separation |
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Gadjah Mada University |
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2014 |
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https://www.scopus.com/inward/record.uri?eid=2-s2.0-84925362413&doi=10.22146%2fajche.49706&partnerID=40&md5=39ef9a29defe307a4809c740e1cbe48b http://eprints.utp.edu.my/31787/ |
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