Synthesis, characterization and physicochemical properties of dual-functional acidic ionic liquids
In this manuscript the synthesis of four new ionic liquids (ILs) having the same cation (1,4-butane sultone methyl-benzimidazole) but different anions (CH3SO3�, CF3SO3�, CF3CO2�, HSO4�) were synthesized and characterized. The ILs was characterized using NMR, elemental analysis (CHNS) and FTI...
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my.utp.eprints.307932022-03-25T07:33:26Z Synthesis, characterization and physicochemical properties of dual-functional acidic ionic liquids Ullah, Z. Bustam, M.A. Man, Z. Shah, S.N. Khan, A.S. Muhammad, N. In this manuscript the synthesis of four new ionic liquids (ILs) having the same cation (1,4-butane sultone methyl-benzimidazole) but different anions (CH3SO3�, CF3SO3�, CF3CO2�, HSO4�) were synthesized and characterized. The ILs was characterized using NMR, elemental analysis (CHNS) and FTIR. The physicochemical properties for these ILs, such as viscosity, density, refractive index, surface tension and thermal stability were analysed in a wide temperature window. Moreover the effects of different anions on the physicochemical properties were studied as well. The density and surface tension values were further used to calculate other properties such as thermal expansion coefficient, surface enthalpy, surface entropy as well as the boiling point and critical temperature of the ILs. The thermal stability analyses were performed from (373.15�773.15) K. © 2016 Elsevier B.V. Elsevier B.V. 2016 Article NonPeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-84981730239&doi=10.1016%2fj.molliq.2016.08.018&partnerID=40&md5=bbabe9541b02dea34a4bf6d7e9a43775 Ullah, Z. and Bustam, M.A. and Man, Z. and Shah, S.N. and Khan, A.S. and Muhammad, N. (2016) Synthesis, characterization and physicochemical properties of dual-functional acidic ionic liquids. Journal of Molecular Liquids, 223 . pp. 81-88. http://eprints.utp.edu.my/30793/ |
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In this manuscript the synthesis of four new ionic liquids (ILs) having the same cation (1,4-butane sultone methyl-benzimidazole) but different anions (CH3SO3�, CF3SO3�, CF3CO2�, HSO4�) were synthesized and characterized. The ILs was characterized using NMR, elemental analysis (CHNS) and FTIR. The physicochemical properties for these ILs, such as viscosity, density, refractive index, surface tension and thermal stability were analysed in a wide temperature window. Moreover the effects of different anions on the physicochemical properties were studied as well. The density and surface tension values were further used to calculate other properties such as thermal expansion coefficient, surface enthalpy, surface entropy as well as the boiling point and critical temperature of the ILs. The thermal stability analyses were performed from (373.15�773.15) K. © 2016 Elsevier B.V. |
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Article |
author |
Ullah, Z. Bustam, M.A. Man, Z. Shah, S.N. Khan, A.S. Muhammad, N. |
spellingShingle |
Ullah, Z. Bustam, M.A. Man, Z. Shah, S.N. Khan, A.S. Muhammad, N. Synthesis, characterization and physicochemical properties of dual-functional acidic ionic liquids |
author_facet |
Ullah, Z. Bustam, M.A. Man, Z. Shah, S.N. Khan, A.S. Muhammad, N. |
author_sort |
Ullah, Z. |
title |
Synthesis, characterization and physicochemical properties of dual-functional acidic ionic liquids |
title_short |
Synthesis, characterization and physicochemical properties of dual-functional acidic ionic liquids |
title_full |
Synthesis, characterization and physicochemical properties of dual-functional acidic ionic liquids |
title_fullStr |
Synthesis, characterization and physicochemical properties of dual-functional acidic ionic liquids |
title_full_unstemmed |
Synthesis, characterization and physicochemical properties of dual-functional acidic ionic liquids |
title_sort |
synthesis, characterization and physicochemical properties of dual-functional acidic ionic liquids |
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Elsevier B.V. |
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2016 |
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https://www.scopus.com/inward/record.uri?eid=2-s2.0-84981730239&doi=10.1016%2fj.molliq.2016.08.018&partnerID=40&md5=bbabe9541b02dea34a4bf6d7e9a43775 http://eprints.utp.edu.my/30793/ |
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