Tripropyl Chitosan iodide-based gel polymer electrolyte as quasi solid-state dye sensitized solar cells
Electrolyte as one of the major components in dye sensitized solar cells (DSSCs) plays an important role in dye regeneration and as the inner charge carrier transport between electrodes. Gel polymer electrolyte is a potential alternative to liquid electrolytes which suffer of leakage and solvent eva...
Saved in:
Main Authors: | , , , |
---|---|
Format: | Article |
Published: |
Trans Tech Publications Ltd
2020
|
Online Access: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85087545159&doi=10.4028%2fwww.scientific.net%2fMSF.997.69&partnerID=40&md5=72d20d42bb1643d896e70c1f61b01d37 http://eprints.utp.edu.my/24711/ |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
id |
my.utp.eprints.24711 |
---|---|
record_format |
eprints |
spelling |
my.utp.eprints.247112021-08-27T05:50:20Z Tripropyl Chitosan iodide-based gel polymer electrolyte as quasi solid-state dye sensitized solar cells Yahya, W.Z.N. Hong, P.Z. Zain, W.Z. Mohamed, N.M. Electrolyte as one of the major components in dye sensitized solar cells (DSSCs) plays an important role in dye regeneration and as the inner charge carrier transport between electrodes. Gel polymer electrolyte is a potential alternative to liquid electrolytes which suffer of leakage and solvent evaporation. In this present research, functionalization of chitosan by the quaternization reaction of chitosan with iodopropane forming tripropyl chitosan iodide is proposed for the preparation of gel polymer electrolyte. Tripropyl chitosan iodide was characterized by nuclear magnetic resonance spectroscopy (NMR), Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA). Four different polymer electrolytes were tested at different compositions in presence of iodide/triiodide redox salt and imidazolium ionic liquid in DSSCs configurations. The results show that the gel polymer electrolyte containing the tripropyl chitosan iodide in presence of 1-propyl-3-methylimidazolium iodide ionic liquid showed better performance with power conversion efficiency of 0.415 as compared to the gel polymer electrolyte film without ionic liquid with power conversion efficiency of 0.075. The results shown the synergistic effects of the polycationic tripropyl chitosan iodide with the ionic liquid 1-propyl-3-methylimidazolium iodide on the photovoltaic performance. © 2020 Trans Tech Publications Ltd, Switzerland. Trans Tech Publications Ltd 2020 Article NonPeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-85087545159&doi=10.4028%2fwww.scientific.net%2fMSF.997.69&partnerID=40&md5=72d20d42bb1643d896e70c1f61b01d37 Yahya, W.Z.N. and Hong, P.Z. and Zain, W.Z. and Mohamed, N.M. (2020) Tripropyl Chitosan iodide-based gel polymer electrolyte as quasi solid-state dye sensitized solar cells. Materials Science Forum, 997 MS . pp. 69-76. http://eprints.utp.edu.my/24711/ |
institution |
Universiti Teknologi Petronas |
building |
UTP Resource Centre |
collection |
Institutional Repository |
continent |
Asia |
country |
Malaysia |
content_provider |
Universiti Teknologi Petronas |
content_source |
UTP Institutional Repository |
url_provider |
http://eprints.utp.edu.my/ |
description |
Electrolyte as one of the major components in dye sensitized solar cells (DSSCs) plays an important role in dye regeneration and as the inner charge carrier transport between electrodes. Gel polymer electrolyte is a potential alternative to liquid electrolytes which suffer of leakage and solvent evaporation. In this present research, functionalization of chitosan by the quaternization reaction of chitosan with iodopropane forming tripropyl chitosan iodide is proposed for the preparation of gel polymer electrolyte. Tripropyl chitosan iodide was characterized by nuclear magnetic resonance spectroscopy (NMR), Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA). Four different polymer electrolytes were tested at different compositions in presence of iodide/triiodide redox salt and imidazolium ionic liquid in DSSCs configurations. The results show that the gel polymer electrolyte containing the tripropyl chitosan iodide in presence of 1-propyl-3-methylimidazolium iodide ionic liquid showed better performance with power conversion efficiency of 0.415 as compared to the gel polymer electrolyte film without ionic liquid with power conversion efficiency of 0.075. The results shown the synergistic effects of the polycationic tripropyl chitosan iodide with the ionic liquid 1-propyl-3-methylimidazolium iodide on the photovoltaic performance. © 2020 Trans Tech Publications Ltd, Switzerland. |
format |
Article |
author |
Yahya, W.Z.N. Hong, P.Z. Zain, W.Z. Mohamed, N.M. |
spellingShingle |
Yahya, W.Z.N. Hong, P.Z. Zain, W.Z. Mohamed, N.M. Tripropyl Chitosan iodide-based gel polymer electrolyte as quasi solid-state dye sensitized solar cells |
author_facet |
Yahya, W.Z.N. Hong, P.Z. Zain, W.Z. Mohamed, N.M. |
author_sort |
Yahya, W.Z.N. |
title |
Tripropyl Chitosan iodide-based gel polymer electrolyte as quasi solid-state dye sensitized solar cells |
title_short |
Tripropyl Chitosan iodide-based gel polymer electrolyte as quasi solid-state dye sensitized solar cells |
title_full |
Tripropyl Chitosan iodide-based gel polymer electrolyte as quasi solid-state dye sensitized solar cells |
title_fullStr |
Tripropyl Chitosan iodide-based gel polymer electrolyte as quasi solid-state dye sensitized solar cells |
title_full_unstemmed |
Tripropyl Chitosan iodide-based gel polymer electrolyte as quasi solid-state dye sensitized solar cells |
title_sort |
tripropyl chitosan iodide-based gel polymer electrolyte as quasi solid-state dye sensitized solar cells |
publisher |
Trans Tech Publications Ltd |
publishDate |
2020 |
url |
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85087545159&doi=10.4028%2fwww.scientific.net%2fMSF.997.69&partnerID=40&md5=72d20d42bb1643d896e70c1f61b01d37 http://eprints.utp.edu.my/24711/ |
_version_ |
1738656628718174208 |
score |
13.159267 |