XPS characterization of tribo-layer formation on the steel lubricated with crude and epoxidized jatropha oil under boundary lubrication

The composition of the tribo-layer formed during sliding of steel in the presence of crude jatropha oil (CJO) and epoxidized jatropha oil (EJO) under boundary lubricant application was investigated using energy-dispersive X-ray and X-ray photo spectroscopy analyses. Utilizing four ball method accord...

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Main Authors: Lubis, A.M.H.S., Ariwahjoedi, B., Sudin, M.
Format: Article
Published: Emerald Group Publishing Ltd. 2017
Online Access:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85020906102&doi=10.1108%2fILT-09-2016-0203&partnerID=40&md5=80b6fbf70ebb39894e84846de5a48f02
http://eprints.utp.edu.my/19818/
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spelling my.utp.eprints.198182018-04-22T12:59:13Z XPS characterization of tribo-layer formation on the steel lubricated with crude and epoxidized jatropha oil under boundary lubrication Lubis, A.M.H.S. Ariwahjoedi, B. Sudin, M. The composition of the tribo-layer formed during sliding of steel in the presence of crude jatropha oil (CJO) and epoxidized jatropha oil (EJO) under boundary lubricant application was investigated using energy-dispersive X-ray and X-ray photo spectroscopy analyses. Utilizing four ball method according to ASTM 4192, EJO showed better wear preventive properties and a lower friction coefficient compared to CJO. CJO and EJO oxidation led to oil chemisorption to steel surface causing formation of protective layers for the steel surface. The layers were constructed from inorganic oxide in the form of iron oxides and silicon oxide together with organic layers in form of aldehyde, ketone, and carboxylic acid. The formation and removal of this layer from rubbing sites are considered to impact wear-preventive and friction behavior of steel lubricated with CJO and EJO. Emerald Group Publishing Ltd. 2017 Article PeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-85020906102&doi=10.1108%2fILT-09-2016-0203&partnerID=40&md5=80b6fbf70ebb39894e84846de5a48f02 Lubis, A.M.H.S. and Ariwahjoedi, B. and Sudin, M. (2017) XPS characterization of tribo-layer formation on the steel lubricated with crude and epoxidized jatropha oil under boundary lubrication. Industrial Lubrication and Tribology, 69 (3). pp. 371-377. http://eprints.utp.edu.my/19818/
institution Universiti Teknologi Petronas
building UTP Resource Centre
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Petronas
content_source UTP Institutional Repository
url_provider http://eprints.utp.edu.my/
description The composition of the tribo-layer formed during sliding of steel in the presence of crude jatropha oil (CJO) and epoxidized jatropha oil (EJO) under boundary lubricant application was investigated using energy-dispersive X-ray and X-ray photo spectroscopy analyses. Utilizing four ball method according to ASTM 4192, EJO showed better wear preventive properties and a lower friction coefficient compared to CJO. CJO and EJO oxidation led to oil chemisorption to steel surface causing formation of protective layers for the steel surface. The layers were constructed from inorganic oxide in the form of iron oxides and silicon oxide together with organic layers in form of aldehyde, ketone, and carboxylic acid. The formation and removal of this layer from rubbing sites are considered to impact wear-preventive and friction behavior of steel lubricated with CJO and EJO.
format Article
author Lubis, A.M.H.S.
Ariwahjoedi, B.
Sudin, M.
spellingShingle Lubis, A.M.H.S.
Ariwahjoedi, B.
Sudin, M.
XPS characterization of tribo-layer formation on the steel lubricated with crude and epoxidized jatropha oil under boundary lubrication
author_facet Lubis, A.M.H.S.
Ariwahjoedi, B.
Sudin, M.
author_sort Lubis, A.M.H.S.
title XPS characterization of tribo-layer formation on the steel lubricated with crude and epoxidized jatropha oil under boundary lubrication
title_short XPS characterization of tribo-layer formation on the steel lubricated with crude and epoxidized jatropha oil under boundary lubrication
title_full XPS characterization of tribo-layer formation on the steel lubricated with crude and epoxidized jatropha oil under boundary lubrication
title_fullStr XPS characterization of tribo-layer formation on the steel lubricated with crude and epoxidized jatropha oil under boundary lubrication
title_full_unstemmed XPS characterization of tribo-layer formation on the steel lubricated with crude and epoxidized jatropha oil under boundary lubrication
title_sort xps characterization of tribo-layer formation on the steel lubricated with crude and epoxidized jatropha oil under boundary lubrication
publisher Emerald Group Publishing Ltd.
publishDate 2017
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-85020906102&doi=10.1108%2fILT-09-2016-0203&partnerID=40&md5=80b6fbf70ebb39894e84846de5a48f02
http://eprints.utp.edu.my/19818/
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score 13.209306