Mesoporous anatase based opto-chemical sensor
Organic dyes immobilized nanocrystalline anatase matrix is synthesized by low-temperature sol-gel method for sensing analysis. It is determined that the thermally stable anatase phase has average crystallite size of 5 nm, low roughness 2 nm, average particle size 5.3 nm, specific surface area of 170...
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| Main Authors: | , , , , |
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| Format: | Article |
| Published: |
Elsevier Ltd
2019
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| Subjects: | |
| Online Access: | http://eprints.utm.my/id/eprint/88146/ http://dx.doi.org/10.1016/j.mssp.2019.05.009 |
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| Summary: | Organic dyes immobilized nanocrystalline anatase matrix is synthesized by low-temperature sol-gel method for sensing analysis. It is determined that the thermally stable anatase phase has average crystallite size of 5 nm, low roughness 2 nm, average particle size 5.3 nm, specific surface area of 170 m2g–1 and refractive index 2. However, after immobilization, smaller average crystallite size ∼3 nm, high roughness 9 nm, smaller average particle size 4.5 nm, larger surface area of 196 m2g–1 and low refractive index 1.8 is determined. The sensitivity 116 RI/pH at 428 nm over pH 1–12 is calculated. The average response time ∼0.3 s in pH 12 is observed. |
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