Preparation and aggregation-induced emission of new 1,3,5-triazine-2,4,6-tricarboxamide with liquid crystal properties

• Main Authors: Umar, Abdulhamid, Shamsuddin, Mustaffa
• Format: Article
• Language: English
• Published: Oriental Scientific Publishing Company 2018
• Subjects: QD Chemistry
• Online Access: http://eprints.utm.my/id/eprint/85957/1/AbdulhamidUmar2018_PreparationandAggregationInducedEmissionofNew.pdf; http://eprints.utm.my/id/eprint/85957/; http://dx.doi.org/10.13005/ojc/340405

The combination of aggregation-induced emission (AIE) and liquid crystal properties generates solid-state efficient luminescent liquid crystal materials.Here in, we reported the synthesis of 1,3,5-triazine-2,4,6-tricarboxamide and utilized it as a supramolecular organic motif for the AIE-active liquid crystal material.The compound exhibits high-intensity emission maxima at 417 and 468 nm in the solid state with excitation at 254 nm, whereas it shows weak emission in the solution phase. Also, this compound behaves as liquid crystalline material and shows columnar hexagonal mesophase with endothermic peaks at 73.4oC, 185.6oC, and exothermic peaks were observed at 181.9oC and 66.1oC with focal conic fan shape texture.The thermal data showed that the compound is stable up to 200oC.