Performance intensification of the polysulfone ultrafiltration membrane by blending with copolymer encompassing novel derivative of poly(styrene-co-maleic anhydride) for heavy metal removal from wastewater
A simple, scalable, novel polymer was synthesized by the aminolysis of poly(styrene-co-maleic anhydride) cumene terminated (PSMAC) using p-aminohippuric acid. The main objective was to perceive the effect of blend ratio of polysulfone (PSF) and poly[styrene-alt-(N-4-benzoylglycine-maleamic acid)] cu...
Saved in:
Main Authors: | , , , , , |
---|---|
Format: | Article |
Published: |
Elsevier B.V.
2018
|
Subjects: | |
Online Access: | http://eprints.utm.my/id/eprint/84288/ https://doi.org/10.1016/j.cej.2018.07.098 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
id |
my.utm.84288 |
---|---|
record_format |
eprints |
spelling |
my.utm.842882019-12-16T03:23:01Z http://eprints.utm.my/id/eprint/84288/ Performance intensification of the polysulfone ultrafiltration membrane by blending with copolymer encompassing novel derivative of poly(styrene-co-maleic anhydride) for heavy metal removal from wastewater Syed Ibrahim, G. P. M. Isloor, Arun M. Asiri, Abdullah Ismail, Ahmad Fauzi Kumar, Rajesha Ahamed, Imran TP Chemical technology A simple, scalable, novel polymer was synthesized by the aminolysis of poly(styrene-co-maleic anhydride) cumene terminated (PSMAC) using p-aminohippuric acid. The main objective was to perceive the effect of blend ratio of polysulfone (PSF) and poly[styrene-alt-(N-4-benzoylglycine-maleamic acid)] cumene terminated (PAH) on morphology and permeation properties of the membranes. The PSF/PAH blend membranes unveiled enriched hydrophilicity, porosity, zeta potential, water uptake and permeability owing to the existence of the hydrophilic PAH. However, the contact angle was not diminished over 20% of PAH ratio as there was an increase of hydrophobic alkyl group density. Differential scanning calorimetry (DSC) was employed for the determination of the glass transition temperature of the blends and the results revealed that the polymer blend is miscible in nature. Moreover, the M-3 membrane was screened for the heavy metal ion removal and achieved removal of 91.5% of Pb2+ and 72.3% of Cd2+ ions, respectively. The adsorption parameters indicated that the Langmuir isotherm model fits well for both Pb2+ and Cd2+ ions adsorption on M-3 membrane. The adsorption capacity attained from Langmuir isotherm model was 19.35 and 9.88 mg/g for Pb2+ and Cd2+ ions correspondingly. Elsevier B.V. 2018 Article PeerReviewed Syed Ibrahim, G. P. and M. Isloor, Arun and M. Asiri, Abdullah and Ismail, Ahmad Fauzi and Kumar, Rajesha and Ahamed, Imran (2018) Performance intensification of the polysulfone ultrafiltration membrane by blending with copolymer encompassing novel derivative of poly(styrene-co-maleic anhydride) for heavy metal removal from wastewater. Chemical Engineering Journal, 353 . pp. 425-4335. ISSN 1385-8947 https://doi.org/10.1016/j.cej.2018.07.098 |
institution |
Universiti Teknologi Malaysia |
building |
UTM Library |
collection |
Institutional Repository |
continent |
Asia |
country |
Malaysia |
content_provider |
Universiti Teknologi Malaysia |
content_source |
UTM Institutional Repository |
url_provider |
http://eprints.utm.my/ |
topic |
TP Chemical technology |
spellingShingle |
TP Chemical technology Syed Ibrahim, G. P. M. Isloor, Arun M. Asiri, Abdullah Ismail, Ahmad Fauzi Kumar, Rajesha Ahamed, Imran Performance intensification of the polysulfone ultrafiltration membrane by blending with copolymer encompassing novel derivative of poly(styrene-co-maleic anhydride) for heavy metal removal from wastewater |
description |
A simple, scalable, novel polymer was synthesized by the aminolysis of poly(styrene-co-maleic anhydride) cumene terminated (PSMAC) using p-aminohippuric acid. The main objective was to perceive the effect of blend ratio of polysulfone (PSF) and poly[styrene-alt-(N-4-benzoylglycine-maleamic acid)] cumene terminated (PAH) on morphology and permeation properties of the membranes. The PSF/PAH blend membranes unveiled enriched hydrophilicity, porosity, zeta potential, water uptake and permeability owing to the existence of the hydrophilic PAH. However, the contact angle was not diminished over 20% of PAH ratio as there was an increase of hydrophobic alkyl group density. Differential scanning calorimetry (DSC) was employed for the determination of the glass transition temperature of the blends and the results revealed that the polymer blend is miscible in nature. Moreover, the M-3 membrane was screened for the heavy metal ion removal and achieved removal of 91.5% of Pb2+ and 72.3% of Cd2+ ions, respectively. The adsorption parameters indicated that the Langmuir isotherm model fits well for both Pb2+ and Cd2+ ions adsorption on M-3 membrane. The adsorption capacity attained from Langmuir isotherm model was 19.35 and 9.88 mg/g for Pb2+ and Cd2+ ions correspondingly. |
format |
Article |
author |
Syed Ibrahim, G. P. M. Isloor, Arun M. Asiri, Abdullah Ismail, Ahmad Fauzi Kumar, Rajesha Ahamed, Imran |
author_facet |
Syed Ibrahim, G. P. M. Isloor, Arun M. Asiri, Abdullah Ismail, Ahmad Fauzi Kumar, Rajesha Ahamed, Imran |
author_sort |
Syed Ibrahim, G. P. |
title |
Performance intensification of the polysulfone ultrafiltration membrane by blending with copolymer encompassing novel derivative of poly(styrene-co-maleic anhydride) for heavy metal removal from wastewater |
title_short |
Performance intensification of the polysulfone ultrafiltration membrane by blending with copolymer encompassing novel derivative of poly(styrene-co-maleic anhydride) for heavy metal removal from wastewater |
title_full |
Performance intensification of the polysulfone ultrafiltration membrane by blending with copolymer encompassing novel derivative of poly(styrene-co-maleic anhydride) for heavy metal removal from wastewater |
title_fullStr |
Performance intensification of the polysulfone ultrafiltration membrane by blending with copolymer encompassing novel derivative of poly(styrene-co-maleic anhydride) for heavy metal removal from wastewater |
title_full_unstemmed |
Performance intensification of the polysulfone ultrafiltration membrane by blending with copolymer encompassing novel derivative of poly(styrene-co-maleic anhydride) for heavy metal removal from wastewater |
title_sort |
performance intensification of the polysulfone ultrafiltration membrane by blending with copolymer encompassing novel derivative of poly(styrene-co-maleic anhydride) for heavy metal removal from wastewater |
publisher |
Elsevier B.V. |
publishDate |
2018 |
url |
http://eprints.utm.my/id/eprint/84288/ https://doi.org/10.1016/j.cej.2018.07.098 |
_version_ |
1654960066795667456 |
score |
13.18916 |