Bio-based hybrid polymers from vinyl ester resin and modified palm oil: Synthesis and characterization
A series of bio-based hybrid thermosets composed of maleinated acrylated epoxidized palm oil (MAEPO) and vinyl ester resin (VE) were produced using free radical-induced cross-linking. The amount of petroleum-based resin which was replaced by bio-resin (MAEPO) was varied from 5 to 20 wt%. The structu...
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Carl Hanser Verlag
2017
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my.utm.763712018-06-29T22:25:05Z http://eprints.utm.my/id/eprint/76371/ Bio-based hybrid polymers from vinyl ester resin and modified palm oil: Synthesis and characterization Fakhari, A. Rahmat, A. R. Wahit, M. U. Arjmandi, R. TP Chemical technology A series of bio-based hybrid thermosets composed of maleinated acrylated epoxidized palm oil (MAEPO) and vinyl ester resin (VE) were produced using free radical-induced cross-linking. The amount of petroleum-based resin which was replaced by bio-resin (MAEPO) was varied from 5 to 20 wt%. The structure of the polymer systems was investigated by scanning electron microscopy and dynamic mechanical analysis. The mechanical properties of the VE/MAEPO resins were studied using tensile, flexural and impact tests. The result obtained from structural analysis revealed that for the polymer hybrids with up to 20 wt% bio-resin content, there is good compatibility between MAEPO and VE as no phase separation was observed for these systems. The prepared eco-friendly bio-based thermosetting resins exhibit remarkable improvement in toughness parameters, such as ductility and impact strength, thereby showing potential for use in composites and nanocomposites applications. Carl Hanser Verlag 2017 Article PeerReviewed Fakhari, A. and Rahmat, A. R. and Wahit, M. U. and Arjmandi, R. (2017) Bio-based hybrid polymers from vinyl ester resin and modified palm oil: Synthesis and characterization. International Polymer Processing, 32 (1). pp. 20-25. ISSN 0930-777X https://www.scopus.com/inward/record.uri?eid=2-s2.0-85014903579&doi=10.3139%2f217.3166&partnerID=40&md5=94115905a60503f65d87a53398f937f2 |
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TP Chemical technology Fakhari, A. Rahmat, A. R. Wahit, M. U. Arjmandi, R. Bio-based hybrid polymers from vinyl ester resin and modified palm oil: Synthesis and characterization |
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A series of bio-based hybrid thermosets composed of maleinated acrylated epoxidized palm oil (MAEPO) and vinyl ester resin (VE) were produced using free radical-induced cross-linking. The amount of petroleum-based resin which was replaced by bio-resin (MAEPO) was varied from 5 to 20 wt%. The structure of the polymer systems was investigated by scanning electron microscopy and dynamic mechanical analysis. The mechanical properties of the VE/MAEPO resins were studied using tensile, flexural and impact tests. The result obtained from structural analysis revealed that for the polymer hybrids with up to 20 wt% bio-resin content, there is good compatibility between MAEPO and VE as no phase separation was observed for these systems. The prepared eco-friendly bio-based thermosetting resins exhibit remarkable improvement in toughness parameters, such as ductility and impact strength, thereby showing potential for use in composites and nanocomposites applications. |
format |
Article |
author |
Fakhari, A. Rahmat, A. R. Wahit, M. U. Arjmandi, R. |
author_facet |
Fakhari, A. Rahmat, A. R. Wahit, M. U. Arjmandi, R. |
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Fakhari, A. |
title |
Bio-based hybrid polymers from vinyl ester resin and modified palm oil: Synthesis and characterization |
title_short |
Bio-based hybrid polymers from vinyl ester resin and modified palm oil: Synthesis and characterization |
title_full |
Bio-based hybrid polymers from vinyl ester resin and modified palm oil: Synthesis and characterization |
title_fullStr |
Bio-based hybrid polymers from vinyl ester resin and modified palm oil: Synthesis and characterization |
title_full_unstemmed |
Bio-based hybrid polymers from vinyl ester resin and modified palm oil: Synthesis and characterization |
title_sort |
bio-based hybrid polymers from vinyl ester resin and modified palm oil: synthesis and characterization |
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Carl Hanser Verlag |
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2017 |
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http://eprints.utm.my/id/eprint/76371/ https://www.scopus.com/inward/record.uri?eid=2-s2.0-85014903579&doi=10.3139%2f217.3166&partnerID=40&md5=94115905a60503f65d87a53398f937f2 |
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13.18916 |