Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-kappa N-2(1),S) nickel(II)
In the asymmetric unit of the title complex, [Ni(C16H14N3OS)(2)], the nickel ion is tetracoordinated in a distorted square-planar geometry by two independent molecules of the ligand which act as mononegative bidentate N,S-donors and form two five-membered chelate rings. The ligands are in trans (E)...
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my.utm.691152017-11-20T08:52:13Z http://eprints.utm.my/id/eprint/69115/ Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-kappa N-2(1),S) nickel(II) Kadir, Faraidoon Karim Shamsuddin, Mustaffa Rosli, Mohd. Mustaqim QD Chemistry In the asymmetric unit of the title complex, [Ni(C16H14N3OS)(2)], the nickel ion is tetracoordinated in a distorted square-planar geometry by two independent molecules of the ligand which act as mononegative bidentate N,S-donors and form two five-membered chelate rings. The ligands are in trans (E) conformations with respect to the C=N bonds. The close approach of hydrogen atoms to the Ni2+ atom suggests anagostic interactions (Ni center dot center dot center dot H-C) are present. The crystal structure is built up by a network of two C-H center dot center dot center dot O interactions. One of the interactions forms inversion dimers and the other links the molecules into infinite chains parallel to [100]. In addition, a weak C-H center dot center dot center dot pi interaction is also present. 2016 Article PeerReviewed Kadir, Faraidoon Karim and Shamsuddin, Mustaffa and Rosli, Mohd. Mustaqim (2016) Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-kappa N-2(1),S) nickel(II). Acta Crystallographica Section E-Crystallographic Communications, 72 . pp. 760-765. ISSN 2056-9890 http://dx.doi.org/10.1107/S2056989016006873 DOI:10.1107/S2056989016006873 |
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QD Chemistry Kadir, Faraidoon Karim Shamsuddin, Mustaffa Rosli, Mohd. Mustaqim Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-kappa N-2(1),S) nickel(II) |
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In the asymmetric unit of the title complex, [Ni(C16H14N3OS)(2)], the nickel ion is tetracoordinated in a distorted square-planar geometry by two independent molecules of the ligand which act as mononegative bidentate N,S-donors and form two five-membered chelate rings. The ligands are in trans (E) conformations with respect to the C=N bonds. The close approach of hydrogen atoms to the Ni2+ atom suggests anagostic interactions (Ni center dot center dot center dot H-C) are present. The crystal structure is built up by a network of two C-H center dot center dot center dot O interactions. One of the interactions forms inversion dimers and the other links the molecules into infinite chains parallel to [100]. In addition, a weak C-H center dot center dot center dot pi interaction is also present. |
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Article |
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Kadir, Faraidoon Karim Shamsuddin, Mustaffa Rosli, Mohd. Mustaqim |
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Kadir, Faraidoon Karim Shamsuddin, Mustaffa Rosli, Mohd. Mustaqim |
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Kadir, Faraidoon Karim |
title |
Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-kappa N-2(1),S) nickel(II) |
title_short |
Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-kappa N-2(1),S) nickel(II) |
title_full |
Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-kappa N-2(1),S) nickel(II) |
title_fullStr |
Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-kappa N-2(1),S) nickel(II) |
title_full_unstemmed |
Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-kappa N-2(1),S) nickel(II) |
title_sort |
crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-kappa n-2(1),s) nickel(ii) |
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2016 |
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http://eprints.utm.my/id/eprint/69115/ http://dx.doi.org/10.1107/S2056989016006873 |
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