Activity of copper and nickel loaded on HZSM-5 zeolite based catalyst for steam reforming of glycerol to hydrogen
The study focuses on hydrogen production via glycerol steam reforming over copper and nickel loaded on HZSM-5 zeolite based catalyst. The catalysts were prepared by using different loading amount of copper (0-10wt%) and nickel (0-10wt%) on HZSM-5 zeolite catalysts through wet impregnation method and...
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my.utm.371992017-09-20T07:44:58Z http://eprints.utm.my/id/eprint/37199/ Activity of copper and nickel loaded on HZSM-5 zeolite based catalyst for steam reforming of glycerol to hydrogen Abdul Halim Yun, Hafizah Mat, Ramli Tuan Abdullah, Tuan Amran Mohamed, Mahadhir Johari, Anwar Ali, Asmadi QD Chemistry The study focuses on hydrogen production via glycerol steam reforming over copper and nickel loaded on HZSM-5 zeolite based catalyst. The catalysts were prepared by using different loading amount of copper (0-10wt%) and nickel (0-10wt%) on HZSM-5 zeolite catalysts through wet impregnation method and was characterized by X-Ray Diffraction (XRD). The performances of catalysts were evaluated in terms of glycerol conversion and hydrogen production at 500°C using 6:1 of water to glycerol molar ratio (WGMR) in a tubular fixed bed reactor. All the catalysts had achieved more than 85% of glycerol conversion except that of 5%Cu loaded on HZSM-5 catalyst. The addition of nickel into 5% Cu/HZSM-5 catalyst had increased the hydrogen yield. Similar trend was observed when copper was added into Ni/HZSM-5 catalyst but using copper loaded on HZSM-5 alone was unable to produce hydrogen compared to using nickel catalyst alone. It showed that copper acted as a promoter for hydrogen production. It was established that a 5wt% of Cu with 10wt% of Ni loaded on HZSM-5 catalyst showed significant improvement in terms of hydrogen yield and gaseous product compositions at selected operating conditions. 2013 Conference or Workshop Item PeerReviewed Abdul Halim Yun, Hafizah and Mat, Ramli and Tuan Abdullah, Tuan Amran and Mohamed, Mahadhir and Johari, Anwar and Ali, Asmadi (2013) Activity of copper and nickel loaded on HZSM-5 zeolite based catalyst for steam reforming of glycerol to hydrogen. In: 3rd International Conference and Exhibition on Sustainable Energy and Advanced Materials (ICE-SEAM 2013) , 2013. |
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QD Chemistry Abdul Halim Yun, Hafizah Mat, Ramli Tuan Abdullah, Tuan Amran Mohamed, Mahadhir Johari, Anwar Ali, Asmadi Activity of copper and nickel loaded on HZSM-5 zeolite based catalyst for steam reforming of glycerol to hydrogen |
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The study focuses on hydrogen production via glycerol steam reforming over copper and nickel loaded on HZSM-5 zeolite based catalyst. The catalysts were prepared by using different loading amount of copper (0-10wt%) and nickel (0-10wt%) on HZSM-5 zeolite catalysts through wet impregnation method and was characterized by X-Ray Diffraction (XRD). The performances of catalysts were evaluated in terms of glycerol conversion and hydrogen production at 500°C using 6:1 of water to glycerol molar ratio (WGMR) in a tubular fixed bed reactor. All the catalysts had achieved more than 85% of glycerol conversion except that of 5%Cu loaded on HZSM-5 catalyst. The addition of nickel into 5% Cu/HZSM-5 catalyst had increased the hydrogen yield. Similar trend was observed when copper was added into Ni/HZSM-5 catalyst but using copper loaded on HZSM-5 alone was unable to produce hydrogen compared to using nickel catalyst alone. It showed that copper acted as a promoter for hydrogen production. It was established that a 5wt% of Cu with 10wt% of Ni loaded on HZSM-5 catalyst showed significant improvement in terms of hydrogen yield and gaseous product compositions at selected operating conditions. |
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Conference or Workshop Item |
author |
Abdul Halim Yun, Hafizah Mat, Ramli Tuan Abdullah, Tuan Amran Mohamed, Mahadhir Johari, Anwar Ali, Asmadi |
author_facet |
Abdul Halim Yun, Hafizah Mat, Ramli Tuan Abdullah, Tuan Amran Mohamed, Mahadhir Johari, Anwar Ali, Asmadi |
author_sort |
Abdul Halim Yun, Hafizah |
title |
Activity of copper and nickel loaded on HZSM-5 zeolite based catalyst for steam reforming of glycerol to hydrogen |
title_short |
Activity of copper and nickel loaded on HZSM-5 zeolite based catalyst for steam reforming of glycerol to hydrogen |
title_full |
Activity of copper and nickel loaded on HZSM-5 zeolite based catalyst for steam reforming of glycerol to hydrogen |
title_fullStr |
Activity of copper and nickel loaded on HZSM-5 zeolite based catalyst for steam reforming of glycerol to hydrogen |
title_full_unstemmed |
Activity of copper and nickel loaded on HZSM-5 zeolite based catalyst for steam reforming of glycerol to hydrogen |
title_sort |
activity of copper and nickel loaded on hzsm-5 zeolite based catalyst for steam reforming of glycerol to hydrogen |
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2013 |
url |
http://eprints.utm.my/id/eprint/37199/ |
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1643650096907157504 |
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13.159267 |