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Dichlorido{4-cyclohexyl-1-[1-(2-pyridylkN)ethylidene] thiosemicarbazidatok2N1,S}methyltin(IV)

The monodeprotonated Schiff base ligand in the title compound, [Sn(CH(3))(C(14)H(19)N(4)S)Cl(2)], N,N',S-chelates to the Sn atom, which is six-coordinated in an octa-hedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are...

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Main Authors: Salam, Md. A., Affan, Md. A., Shamsuddin, Mustaffa, Ng, S. W.
Format: Article
Published: International Union of Crystallography 2011
Subjects:
Q Science
Online Access:http://eprints.utm.my/id/eprint/29062/
http://dx.doi.org/10.1107/S1600536810049214
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spelling my.utm.290622020-10-22T04:04:06Z http://eprints.utm.my/id/eprint/29062/ Dichlorido{4-cyclohexyl-1-[1-(2-pyridylkN)ethylidene] thiosemicarbazidatok2N1,S}methyltin(IV) Salam, Md. A. Affan, Md. A. Shamsuddin, Mustaffa Ng, S. W. Q Science The monodeprotonated Schiff base ligand in the title compound, [Sn(CH(3))(C(14)H(19)N(4)S)Cl(2)], N,N',S-chelates to the Sn atom, which is six-coordinated in an octa-hedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent mol-ecule, the hydrogen bond giving rise to a helical chain extending parallel to [100]. International Union of Crystallography 2011 Article PeerReviewed Salam, Md. A. and Affan, Md. A. and Shamsuddin, Mustaffa and Ng, S. W. (2011) Dichlorido{4-cyclohexyl-1-[1-(2-pyridylkN)ethylidene] thiosemicarbazidatok2N1,S}methyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 67 (1). p. 570. ISSN 1600-5368 http://dx.doi.org/10.1107/S1600536810049214 DOI:10.1107/S1600536810049214
institution Universiti Teknologi Malaysia
building UTM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Malaysia
content_source UTM Institutional Repository
url_provider http://eprints.utm.my/
topic Q Science
spellingShingle Q Science
Salam, Md. A.
Affan, Md. A.
Shamsuddin, Mustaffa
Ng, S. W.
Dichlorido{4-cyclohexyl-1-[1-(2-pyridylkN)ethylidene] thiosemicarbazidatok2N1,S}methyltin(IV)
description The monodeprotonated Schiff base ligand in the title compound, [Sn(CH(3))(C(14)H(19)N(4)S)Cl(2)], N,N',S-chelates to the Sn atom, which is six-coordinated in an octa-hedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent mol-ecule, the hydrogen bond giving rise to a helical chain extending parallel to [100].
format Article
author Salam, Md. A.
Affan, Md. A.
Shamsuddin, Mustaffa
Ng, S. W.
author_facet Salam, Md. A.
Affan, Md. A.
Shamsuddin, Mustaffa
Ng, S. W.
author_sort Salam, Md. A.
title Dichlorido{4-cyclohexyl-1-[1-(2-pyridylkN)ethylidene] thiosemicarbazidatok2N1,S}methyltin(IV)
title_short Dichlorido{4-cyclohexyl-1-[1-(2-pyridylkN)ethylidene] thiosemicarbazidatok2N1,S}methyltin(IV)
title_full Dichlorido{4-cyclohexyl-1-[1-(2-pyridylkN)ethylidene] thiosemicarbazidatok2N1,S}methyltin(IV)
title_fullStr Dichlorido{4-cyclohexyl-1-[1-(2-pyridylkN)ethylidene] thiosemicarbazidatok2N1,S}methyltin(IV)
title_full_unstemmed Dichlorido{4-cyclohexyl-1-[1-(2-pyridylkN)ethylidene] thiosemicarbazidatok2N1,S}methyltin(IV)
title_sort dichlorido{4-cyclohexyl-1-[1-(2-pyridylkn)ethylidene] thiosemicarbazidatok2n1,s}methyltin(iv)
publisher International Union of Crystallography
publishDate 2011
url http://eprints.utm.my/id/eprint/29062/
http://dx.doi.org/10.1107/S1600536810049214
_version_ 1681489436156624896
score 13.19449

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