Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-N)ethylidene]thiosemicarbazidato-2N1,S}methyltin(IV)
The monodeprotonated Schiff base ligand in the title compound, [Sn(CH3)(C14H19N4S)Cl2], N,N',S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are positioned...
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International Union of Crystallography
2010
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my.utm.270812017-02-13T01:41:34Z http://eprints.utm.my/id/eprint/27081/ Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-N)ethylidene]thiosemicarbazidato-2N1,S}methyltin(IV) Shamsuddin, Mustaffa Salam, Md. Abdus Affan, Md. Abu Seik Weng, Ng Q Science The monodeprotonated Schiff base ligand in the title compound, [Sn(CH3)(C14H19N4S)Cl2], N,N',S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent molecule, the hydrogen bond giving rise to a helical chain extending parallel to [100]. International Union of Crystallography 2010 Article PeerReviewed Shamsuddin, Mustaffa and Salam, Md. Abdus and Affan, Md. Abu and Seik Weng, Ng (2010) Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-N)ethylidene]thiosemicarbazidato-2N1,S}methyltin(IV). Acta Crystallographica Section E-Structure Reports, E66 (5). p. 570. ISSN 1600-5368 http://dx.doi.org/10.1107/S1600536810014443 DOI:10.1107/S1600536810014443 |
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Q Science Shamsuddin, Mustaffa Salam, Md. Abdus Affan, Md. Abu Seik Weng, Ng Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-N)ethylidene]thiosemicarbazidato-2N1,S}methyltin(IV) |
| description |
The monodeprotonated Schiff base ligand in the title compound, [Sn(CH3)(C14H19N4S)Cl2], N,N',S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent molecule, the hydrogen bond giving rise to a helical chain extending parallel to [100]. |
| format |
Article |
| author |
Shamsuddin, Mustaffa Salam, Md. Abdus Affan, Md. Abu Seik Weng, Ng |
| author_facet |
Shamsuddin, Mustaffa Salam, Md. Abdus Affan, Md. Abu Seik Weng, Ng |
| author_sort |
Shamsuddin, Mustaffa |
| title |
Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-N)ethylidene]thiosemicarbazidato-2N1,S}methyltin(IV) |
| title_short |
Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-N)ethylidene]thiosemicarbazidato-2N1,S}methyltin(IV) |
| title_full |
Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-N)ethylidene]thiosemicarbazidato-2N1,S}methyltin(IV) |
| title_fullStr |
Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-N)ethylidene]thiosemicarbazidato-2N1,S}methyltin(IV) |
| title_full_unstemmed |
Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-N)ethylidene]thiosemicarbazidato-2N1,S}methyltin(IV) |
| title_sort |
dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-n)ethylidene]thiosemicarbazidato-2n1,s}methyltin(iv) |
| publisher |
International Union of Crystallography |
| publishDate |
2010 |
| url |
http://eprints.utm.my/id/eprint/27081/ http://dx.doi.org/10.1107/S1600536810014443 |
| _version_ |
1643647943839842304 |
| score |
13.160551 |