Evaluation of surface properties and separation performance of NF and RO membranes for phthalates removal
Many studies indicated that phthalates, a common plasticizer, lurk silently in water bodies and can potentially harm living organisms. Therefore, removing phthalates from water sources prior to consumption is crucial. This study aims to evaluate the performance of several commercial nanofiltrations...
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Online Access: | http://eprints.utm.my/105774/1/LauWoeiJye2023_EvaluationofSurfacePropertiesandSeparation.pdf http://eprints.utm.my/105774/ http://dx.doi.org/10.3390/membranes13040413 |
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my.utm.1057742024-05-15T07:14:19Z http://eprints.utm.my/105774/ Evaluation of surface properties and separation performance of NF and RO membranes for phthalates removal Lim, En Qi Seah, Mei Qun Lau, Woei Jye Hasbullah, Hasrinah Goh, Pei Sean Ismail, Ahmad Fauzi Emadzadeh, Daryoush Q Science (General) Many studies indicated that phthalates, a common plasticizer, lurk silently in water bodies and can potentially harm living organisms. Therefore, removing phthalates from water sources prior to consumption is crucial. This study aims to evaluate the performance of several commercial nanofiltrations (NF) (i.e., NF3 and Duracid) and reverse osmosis (RO) membranes (i.e., SW30XLE and BW30) in removing phthalates from simulated solutions and further correlate the intrinsic properties of membranes (e.g., surface chemistry, morphology, and hydrophilicity) with the phthalates removal. Two types of phthalates, i.e., dibutyl phthalate (DBP) and butyl benzyl phthalate (BBP), were used in this work, and the effects of pH (ranging from 3 to 10) on the membrane performance were studied. The experimental findings showed that the NF3 membrane could yield the best DBP (92.5–98.8%) and BBP rejection (88.7–91.7%) regardless of pH, and these excellent results are in good agreement with the surface properties of the membrane, i.e., low water contact angle (hydrophilicity) and appropriate pore size. Moreover, the NF3 membrane with a lower polyamide cross-linking degree also exhibited significantly higher water flux compared to the RO membranes. Further investigation indicated that the surface of the NF3 membrane was severely covered by foulants after 4-h filtration of DBP solution compared to the BBP solution. This could be attributed to the high concentration of DBP presented in the feed solution owing to its high-water solubility (13 ppm) compared to BBP (2.69 ppm). Further research is still needed to study the effect of other compounds (e.g., dissolved ions and organic/inorganic matters that might be present in water) on the performance of membranes in removing phthalates. MDPI 2023-04 Article PeerReviewed application/pdf en http://eprints.utm.my/105774/1/LauWoeiJye2023_EvaluationofSurfacePropertiesandSeparation.pdf Lim, En Qi and Seah, Mei Qun and Lau, Woei Jye and Hasbullah, Hasrinah and Goh, Pei Sean and Ismail, Ahmad Fauzi and Emadzadeh, Daryoush (2023) Evaluation of surface properties and separation performance of NF and RO membranes for phthalates removal. Membranes, 13 (4). pp. 1-13. ISSN 2077-0375 http://dx.doi.org/10.3390/membranes13040413 DOI:10.3390/membranes13040413 |
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Q Science (General) Lim, En Qi Seah, Mei Qun Lau, Woei Jye Hasbullah, Hasrinah Goh, Pei Sean Ismail, Ahmad Fauzi Emadzadeh, Daryoush Evaluation of surface properties and separation performance of NF and RO membranes for phthalates removal |
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Many studies indicated that phthalates, a common plasticizer, lurk silently in water bodies and can potentially harm living organisms. Therefore, removing phthalates from water sources prior to consumption is crucial. This study aims to evaluate the performance of several commercial nanofiltrations (NF) (i.e., NF3 and Duracid) and reverse osmosis (RO) membranes (i.e., SW30XLE and BW30) in removing phthalates from simulated solutions and further correlate the intrinsic properties of membranes (e.g., surface chemistry, morphology, and hydrophilicity) with the phthalates removal. Two types of phthalates, i.e., dibutyl phthalate (DBP) and butyl benzyl phthalate (BBP), were used in this work, and the effects of pH (ranging from 3 to 10) on the membrane performance were studied. The experimental findings showed that the NF3 membrane could yield the best DBP (92.5–98.8%) and BBP rejection (88.7–91.7%) regardless of pH, and these excellent results are in good agreement with the surface properties of the membrane, i.e., low water contact angle (hydrophilicity) and appropriate pore size. Moreover, the NF3 membrane with a lower polyamide cross-linking degree also exhibited significantly higher water flux compared to the RO membranes. Further investigation indicated that the surface of the NF3 membrane was severely covered by foulants after 4-h filtration of DBP solution compared to the BBP solution. This could be attributed to the high concentration of DBP presented in the feed solution owing to its high-water solubility (13 ppm) compared to BBP (2.69 ppm). Further research is still needed to study the effect of other compounds (e.g., dissolved ions and organic/inorganic matters that might be present in water) on the performance of membranes in removing phthalates. |
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Article |
author |
Lim, En Qi Seah, Mei Qun Lau, Woei Jye Hasbullah, Hasrinah Goh, Pei Sean Ismail, Ahmad Fauzi Emadzadeh, Daryoush |
author_facet |
Lim, En Qi Seah, Mei Qun Lau, Woei Jye Hasbullah, Hasrinah Goh, Pei Sean Ismail, Ahmad Fauzi Emadzadeh, Daryoush |
author_sort |
Lim, En Qi |
title |
Evaluation of surface properties and separation performance of NF and RO membranes for phthalates removal |
title_short |
Evaluation of surface properties and separation performance of NF and RO membranes for phthalates removal |
title_full |
Evaluation of surface properties and separation performance of NF and RO membranes for phthalates removal |
title_fullStr |
Evaluation of surface properties and separation performance of NF and RO membranes for phthalates removal |
title_full_unstemmed |
Evaluation of surface properties and separation performance of NF and RO membranes for phthalates removal |
title_sort |
evaluation of surface properties and separation performance of nf and ro membranes for phthalates removal |
publisher |
MDPI |
publishDate |
2023 |
url |
http://eprints.utm.my/105774/1/LauWoeiJye2023_EvaluationofSurfacePropertiesandSeparation.pdf http://eprints.utm.my/105774/ http://dx.doi.org/10.3390/membranes13040413 |
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13.188404 |