A new solubility model for competing effects of three solvents: water, ethanol, and supercritical carbon dioxide
This study aims to develop a new semi-empirical model to fit solute solubility in a mixture of solvents, viz. supercritical carbon dioxide, ethanol, and water, as well as to evaluate the effects of competing solvents on solubility. Therefore, the model was assessed by fitting the published solubilit...
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2022
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my.utm.1041112024-01-17T01:12:38Z http://eprints.utm.my/104111/ A new solubility model for competing effects of three solvents: water, ethanol, and supercritical carbon dioxide Nicky Rahmana Putra, Nicky Rahmana Putra Dwila Nur Rizkiyah, Dwila Nur Rizkiyah Idham, Zuhaili Jumakir, Jumakir Waluyo, Waluyo Mohd. Faizal, Azrul Nurfaiz Ahmad Zaini, Muhammad Abbas Che Yunus, Mohd. Azizi Q Science (General) This study aims to develop a new semi-empirical model to fit solute solubility in a mixture of solvents, viz. supercritical carbon dioxide, ethanol, and water, as well as to evaluate the effects of competing solvents on solubility. Therefore, the model was assessed by fitting the published solubility data and comparing it with the established semi-empirical models. The findings revealed that the new model gave the highest coefficient of determination, R2 of 0.96 and had the lowest AARD (i.e., 3.88%), compared to other models. To conclude, the new model is feasible in determining three solvents’ solvation effects in one system. Taylor and Francis Group 2022 Article PeerReviewed Nicky Rahmana Putra, Nicky Rahmana Putra and Dwila Nur Rizkiyah, Dwila Nur Rizkiyah and Idham, Zuhaili and Jumakir, Jumakir and Waluyo, Waluyo and Mohd. Faizal, Azrul Nurfaiz and Ahmad Zaini, Muhammad Abbas and Che Yunus, Mohd. Azizi (2022) A new solubility model for competing effects of three solvents: water, ethanol, and supercritical carbon dioxide. Separation Science and Technology, 57 (14). pp. 2269-2275. ISSN 0149-6395 http://dx.doi.org/10.1080/01496395.2022.2045317 DOI:10.1080/01496395.2022.2045317 |
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Q Science (General) Nicky Rahmana Putra, Nicky Rahmana Putra Dwila Nur Rizkiyah, Dwila Nur Rizkiyah Idham, Zuhaili Jumakir, Jumakir Waluyo, Waluyo Mohd. Faizal, Azrul Nurfaiz Ahmad Zaini, Muhammad Abbas Che Yunus, Mohd. Azizi A new solubility model for competing effects of three solvents: water, ethanol, and supercritical carbon dioxide |
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This study aims to develop a new semi-empirical model to fit solute solubility in a mixture of solvents, viz. supercritical carbon dioxide, ethanol, and water, as well as to evaluate the effects of competing solvents on solubility. Therefore, the model was assessed by fitting the published solubility data and comparing it with the established semi-empirical models. The findings revealed that the new model gave the highest coefficient of determination, R2 of 0.96 and had the lowest AARD (i.e., 3.88%), compared to other models. To conclude, the new model is feasible in determining three solvents’ solvation effects in one system. |
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Nicky Rahmana Putra, Nicky Rahmana Putra Dwila Nur Rizkiyah, Dwila Nur Rizkiyah Idham, Zuhaili Jumakir, Jumakir Waluyo, Waluyo Mohd. Faizal, Azrul Nurfaiz Ahmad Zaini, Muhammad Abbas Che Yunus, Mohd. Azizi |
author_facet |
Nicky Rahmana Putra, Nicky Rahmana Putra Dwila Nur Rizkiyah, Dwila Nur Rizkiyah Idham, Zuhaili Jumakir, Jumakir Waluyo, Waluyo Mohd. Faizal, Azrul Nurfaiz Ahmad Zaini, Muhammad Abbas Che Yunus, Mohd. Azizi |
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Nicky Rahmana Putra, Nicky Rahmana Putra |
title |
A new solubility model for competing effects of three solvents: water, ethanol, and supercritical carbon dioxide |
title_short |
A new solubility model for competing effects of three solvents: water, ethanol, and supercritical carbon dioxide |
title_full |
A new solubility model for competing effects of three solvents: water, ethanol, and supercritical carbon dioxide |
title_fullStr |
A new solubility model for competing effects of three solvents: water, ethanol, and supercritical carbon dioxide |
title_full_unstemmed |
A new solubility model for competing effects of three solvents: water, ethanol, and supercritical carbon dioxide |
title_sort |
new solubility model for competing effects of three solvents: water, ethanol, and supercritical carbon dioxide |
publisher |
Taylor and Francis Group |
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2022 |
url |
http://eprints.utm.my/104111/ http://dx.doi.org/10.1080/01496395.2022.2045317 |
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1789424380616376320 |
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13.19449 |