Use of synthetic wollastonite nanofibers in enhancing mechanical, thermal, and flammability properties of polyoxymethylene nanocomposites

• Main Authors: Wong, Joon Fatt, Chan, Jia Xin, Hassan, Azman, Mohamad, Zurina, Hashim, Shahrir, Abd. Razak, Jeefferie, Ching, Yern Chee, Yunos, Zaini, Yahaya, Ridwan
• Format: Article
• Published: John Wiley and Sons Inc 2022
• Subjects: Q Science (General); TJ Mechanical engineering and machinery
• Online Access: http://eprints.utm.my/103698/; http://dx.doi.org/10.1002/pc.26902

This study investigates the mechanical, thermal, and flammability properties of synthetic wollastonite nanofibers (SWN) reinforced polyoxymethylene (POM) nanocomposites. SWN has been added into the POM nanocomposites in the range of 0.5–3 phr via melt blending. The mechanical properties were investigated through tensile and impact tests with scanning electron microscopy and energy dispersive X-ray analysis. The thermal characterization was performed by thermogravimetry analysis and differential scanning calorimetry. Flame retardancy of nanocomposites was studied through cone calorimetry analysis and limiting oxygen index test. The tensile strength of nanocomposites improved by 5.88% at 1 phr SWN content, whereas Young's modulus increased with increasing content. The thermal stability of nanocomposites was enhanced as indicated by the higher initial degradation temperature, which rose about 22°C at 1 phr SWN content. The POM/SWN nanocomposites exhibited better mechanical strength despite their lower crystallinity due to the substantial reinforcing effect of SWN. The flame retardancy of nanocomposites improved, as indicated by the reduction of peak heat release rate from the cone calorimetry test. This study shows that SWN has simultaneously enhanced the mechanical strength, thermal stability, and flame retardancy of POM nanocomposites and has the potential in automotive applications.