1-[(E)-(3-Hydroxy-4-methoxybenzylidene)amino]- 3-methylthiourea
In the title thiosemicarbazone Schiff base compound, C10H13N3O2S, the dihedral angle between the benzene ring and methyl carbothioamide side arm was found to be 17.4 (4)�. The presence of two intramolecular hydrogen bonds is noted, namely hydroxy-O—H� � �O(methoxy) and amine-N—H� � �N(imine). In...
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International Union of Crystallography
2016
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my.usm.eprints.37935 http://eprints.usm.my/37935/ 1-[(E)-(3-Hydroxy-4-methoxybenzylidene)amino]- 3-methylthiourea Arafath, Md. Azharul Adam, Farook Razali, Mohd. R. QD1-999 Chemistry In the title thiosemicarbazone Schiff base compound, C10H13N3O2S, the dihedral angle between the benzene ring and methyl carbothioamide side arm was found to be 17.4 (4)�. The presence of two intramolecular hydrogen bonds is noted, namely hydroxy-O—H� � �O(methoxy) and amine-N—H� � �N(imine). In the crystal, pairwise amine-N—H� � �S hydrogen bonds give rise to centrosymmetric {� � �HNCS}2 synthons, which lead to dimeric aggregates. International Union of Crystallography 2016 Article PeerReviewed application/pdf en http://eprints.usm.my/37935/1/1-%5B%28E%29-%283-Hydroxy-4-methoxybenzylidene%29amino%5D-.pdf Arafath, Md. Azharul and Adam, Farook and Razali, Mohd. R. (2016) 1-[(E)-(3-Hydroxy-4-methoxybenzylidene)amino]- 3-methylthiourea. IUCrData, 2016 (1). pp. 1-6. ISSN 2414-3146 http://dx.doi.org/10.1107/S2414314616015996 |
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QD1-999 Chemistry Arafath, Md. Azharul Adam, Farook Razali, Mohd. R. 1-[(E)-(3-Hydroxy-4-methoxybenzylidene)amino]- 3-methylthiourea |
| description |
In the title thiosemicarbazone Schiff base compound, C10H13N3O2S, the dihedral
angle between the benzene ring and methyl carbothioamide side arm was found
to be 17.4 (4)�. The presence of two intramolecular hydrogen bonds is noted,
namely hydroxy-O—H� � �O(methoxy) and amine-N—H� � �N(imine). In the
crystal, pairwise amine-N—H� � �S hydrogen bonds give rise to centrosymmetric
{� � �HNCS}2 synthons, which lead to dimeric aggregates. |
| format |
Article |
| author |
Arafath, Md. Azharul Adam, Farook Razali, Mohd. R. |
| author_facet |
Arafath, Md. Azharul Adam, Farook Razali, Mohd. R. |
| author_sort |
Arafath, Md. Azharul |
| title |
1-[(E)-(3-Hydroxy-4-methoxybenzylidene)amino]-
3-methylthiourea |
| title_short |
1-[(E)-(3-Hydroxy-4-methoxybenzylidene)amino]-
3-methylthiourea |
| title_full |
1-[(E)-(3-Hydroxy-4-methoxybenzylidene)amino]-
3-methylthiourea |
| title_fullStr |
1-[(E)-(3-Hydroxy-4-methoxybenzylidene)amino]-
3-methylthiourea |
| title_full_unstemmed |
1-[(E)-(3-Hydroxy-4-methoxybenzylidene)amino]-
3-methylthiourea |
| title_sort |
1-[(e)-(3-hydroxy-4-methoxybenzylidene)amino]-
3-methylthiourea |
| publisher |
International Union of Crystallography |
| publishDate |
2016 |
| url |
http://eprints.usm.my/37935/1/1-%5B%28E%29-%283-Hydroxy-4-methoxybenzylidene%29amino%5D-.pdf http://eprints.usm.my/37935/ http://dx.doi.org/10.1107/S2414314616015996 |
| _version_ |
1643709211209629696 |
| score |
13.188404 |