1-(2,4-Dinitrophenyl)-2-[(E)-(3,4,5-trimethoxybenzylidene)] hydrazine
Molecules of the title compound, C16H16N4O7, are not planar with a dihedral angle of 5.50 (11)� between the substituted benzene rings. The two meta-methoxy groups of the 3,4,5- trimethoxybenzene moiety lie in the plane of the attached ring [Cmethyl–O–C–C torsion angles �0.1 (4)� and �3.7 (3)�] w...
Saved in:
Main Authors: | , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2014
|
Subjects: | |
Online Access: | http://eprints.usm.my/37933/1/1-%282%2C4-Dinitrophenyl%29-2-%5B%28E%29-%283%2C4%2C5-trimethoxybenzylidene%29%5Dhydrazine.pdf http://eprints.usm.my/37933/ https://doi.org/10.1107/S1600536814001238 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
id |
my.usm.eprints.37933 |
---|---|
record_format |
eprints |
spelling |
my.usm.eprints.37933 http://eprints.usm.my/37933/ 1-(2,4-Dinitrophenyl)-2-[(E)-(3,4,5-trimethoxybenzylidene)] hydrazine Chantrapromma, Suchada Ruanwas, Pumsak Boonnak, Nawong Chidan Kumar, C. S. Hoong, Kun Fun QC1 Physics (General) Molecules of the title compound, C16H16N4O7, are not planar with a dihedral angle of 5.50 (11)� between the substituted benzene rings. The two meta-methoxy groups of the 3,4,5- trimethoxybenzene moiety lie in the plane of the attached ring [Cmethyl–O–C–C torsion angles �0.1 (4)� and �3.7 (3)�] while the para-methoxy substituent lies out of the plane [Cmethyl— O—C—C, �86.0 (3)�]. An intramolecular N—H� � �O hydrogen bond involving the 2-nitro substituent generates an S(6) ring motif. In the crystal structure, molecules are linked by weak C—H� � �O interactions into screw chains, that are arranged into a sheet parallel to the bc plane. These sheets are connected by �–� stacking interactions between the nitro and methoxy substituted aromatic rings with a centroid– centroid separation of 3.9420 (13) A ° . C—H� � �� contacts further stabilize the two-dimensional network. International Union of Crystallography 2014 Article PeerReviewed application/pdf en http://eprints.usm.my/37933/1/1-%282%2C4-Dinitrophenyl%29-2-%5B%28E%29-%283%2C4%2C5-trimethoxybenzylidene%29%5Dhydrazine.pdf Chantrapromma, Suchada and Ruanwas, Pumsak and Boonnak, Nawong and Chidan Kumar, C. S. and Hoong, Kun Fun (2014) 1-(2,4-Dinitrophenyl)-2-[(E)-(3,4,5-trimethoxybenzylidene)] hydrazine. Acta Crystallographica Section E: Crystallographic Communications, 2014 (E70). 0188-0189. ISSN 1600-5368 https://doi.org/10.1107/S1600536814001238 |
institution |
Universiti Sains Malaysia |
building |
Hamzah Sendut Library |
collection |
Institutional Repository |
continent |
Asia |
country |
Malaysia |
content_provider |
Universiti Sains Malaysia |
content_source |
USM Institutional Repository |
url_provider |
http://eprints.usm.my/ |
language |
English |
topic |
QC1 Physics (General) |
spellingShingle |
QC1 Physics (General) Chantrapromma, Suchada Ruanwas, Pumsak Boonnak, Nawong Chidan Kumar, C. S. Hoong, Kun Fun 1-(2,4-Dinitrophenyl)-2-[(E)-(3,4,5-trimethoxybenzylidene)] hydrazine |
description |
Molecules of the title compound, C16H16N4O7, are not planar
with a dihedral angle of 5.50 (11)� between the substituted
benzene rings. The two meta-methoxy groups of the 3,4,5-
trimethoxybenzene moiety lie in the plane of the attached ring
[Cmethyl–O–C–C torsion angles �0.1 (4)� and �3.7 (3)�] while
the para-methoxy substituent lies out of the plane [Cmethyl—
O—C—C, �86.0 (3)�]. An intramolecular N—H� � �O
hydrogen bond involving the 2-nitro substituent generates
an S(6) ring motif. In the crystal structure, molecules are
linked by weak C—H� � �O interactions into screw chains, that
are arranged into a sheet parallel to the bc plane. These sheets
are connected by �–� stacking interactions between the nitro
and methoxy substituted aromatic rings with a centroid–
centroid separation of 3.9420 (13) A ° . C—H� � �� contacts
further stabilize the two-dimensional network. |
format |
Article |
author |
Chantrapromma, Suchada Ruanwas, Pumsak Boonnak, Nawong Chidan Kumar, C. S. Hoong, Kun Fun |
author_facet |
Chantrapromma, Suchada Ruanwas, Pumsak Boonnak, Nawong Chidan Kumar, C. S. Hoong, Kun Fun |
author_sort |
Chantrapromma, Suchada |
title |
1-(2,4-Dinitrophenyl)-2-[(E)-(3,4,5-trimethoxybenzylidene)]
hydrazine |
title_short |
1-(2,4-Dinitrophenyl)-2-[(E)-(3,4,5-trimethoxybenzylidene)]
hydrazine |
title_full |
1-(2,4-Dinitrophenyl)-2-[(E)-(3,4,5-trimethoxybenzylidene)]
hydrazine |
title_fullStr |
1-(2,4-Dinitrophenyl)-2-[(E)-(3,4,5-trimethoxybenzylidene)]
hydrazine |
title_full_unstemmed |
1-(2,4-Dinitrophenyl)-2-[(E)-(3,4,5-trimethoxybenzylidene)]
hydrazine |
title_sort |
1-(2,4-dinitrophenyl)-2-[(e)-(3,4,5-trimethoxybenzylidene)]
hydrazine |
publisher |
International Union of Crystallography |
publishDate |
2014 |
url |
http://eprints.usm.my/37933/1/1-%282%2C4-Dinitrophenyl%29-2-%5B%28E%29-%283%2C4%2C5-trimethoxybenzylidene%29%5Dhydrazine.pdf http://eprints.usm.my/37933/ https://doi.org/10.1107/S1600536814001238 |
_version_ |
1643709210622427136 |
score |
13.160551 |