(E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine- 1-carbothioamide
In the title compound, C 14 H 18 ClN 3 OS, the phenol ring is almost coplanar with the hydrazinecarbothioamide moiety, making a dihedral angle of 6.92 (8)°. The cyclohexane ring has a chair conformation and the conformation about the C=N bond is E . In the crystal, molecules are linked by N—H...O an...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2017
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| Subjects: | |
| Online Access: | http://eprints.usm.my/36908/1/%28E-2-%285-Chloro-2-hydroxybenzylidene%29__su4104.pdf http://eprints.usm.my/36908/ https://doi.org/10.1107/S2414314616019970 |
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| Summary: | In the title compound, C 14 H 18 ClN 3 OS, the phenol ring is almost coplanar with the hydrazinecarbothioamide moiety, making a dihedral angle of 6.92 (8)°. The cyclohexane ring has a chair conformation and the conformation about the C=N bond is E . In the crystal, molecules are linked by N—H...O and O—H...S hydrogen bonds, forming inversion dimers with an R2² (14) ring motif flanked by two R2² (6) ring motifs. The dimers are linked by short Cl...Cl interactions, forming layers parallel to the ab plane.
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