A novel polymer inclusion membranes based optode for sensitive determination of Al3+ ions

A novel approach for the determination of Al3+ from aqueous samples was developed using an optode membrane produced by physical inclusion of Al3+ selective reagent, which is morin into a plasticized poly(vinyl chloride). The inclusion of Triton X-100 was found to be valuable and useful for enhancing...

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Main Authors: F.B.M, Suah,, M, Ahmad,, L.Y., Heng,
Format: Article
Language:en_US
Published: Elsevier 2015
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Online Access:http://ddms.usim.edu.my/handle/123456789/8493
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spelling my.usim-84932017-02-23T04:56:46Z A novel polymer inclusion membranes based optode for sensitive determination of Al3+ ions F.B.M, Suah, M, Ahmad, L.Y., Heng, Al3+ determination Morin Optode Polymer inclusion membrane Triton; X-100 A novel approach for the determination of Al3+ from aqueous samples was developed using an optode membrane produced by physical inclusion of Al3+ selective reagent, which is morin into a plasticized poly(vinyl chloride). The inclusion of Triton X-100 was found to be valuable and useful for enhancing the sorption of Al3+ ions from liquid phase into the membrane phase, thus increasing the intensity of optode's absorption. The optode showed a linear increase in the absorbance at λmax = 425 nm over the concentration range of 1.85 × 10-6-1.1 × 10-4 mol L-1 (0.05-3 μg mL-1) of Al3+ ions in aqueous solution after 5 min. The limit of detection was determined to be 1.04 × 10-6 mol L-1 (0.028 μg mL-1). The optode developed in the present work was easily prepared and found to be stable, has good mechanical strength, sensitive and reusable. In addition, the optode was tested for Al3+ determination in lake water, river water and pharmaceutical samples, which the result was satisfactory. 2015-06-25T02:48:39Z 2015-06-25T02:48:39Z 2015 Article 13861425 http://ddms.usim.edu.my/handle/123456789/8493 en_US Elsevier
institution Universiti Sains Islam Malaysia
building USIM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universit Sains Islam i Malaysia
content_source USIM Institutional Repository
url_provider http://ddms.usim.edu.my/
language en_US
topic Al3+ determination
Morin
Optode
Polymer inclusion membrane
Triton; X-100
spellingShingle Al3+ determination
Morin
Optode
Polymer inclusion membrane
Triton; X-100
F.B.M, Suah,
M, Ahmad,
L.Y., Heng,
A novel polymer inclusion membranes based optode for sensitive determination of Al3+ ions
description A novel approach for the determination of Al3+ from aqueous samples was developed using an optode membrane produced by physical inclusion of Al3+ selective reagent, which is morin into a plasticized poly(vinyl chloride). The inclusion of Triton X-100 was found to be valuable and useful for enhancing the sorption of Al3+ ions from liquid phase into the membrane phase, thus increasing the intensity of optode's absorption. The optode showed a linear increase in the absorbance at λmax = 425 nm over the concentration range of 1.85 × 10-6-1.1 × 10-4 mol L-1 (0.05-3 μg mL-1) of Al3+ ions in aqueous solution after 5 min. The limit of detection was determined to be 1.04 × 10-6 mol L-1 (0.028 μg mL-1). The optode developed in the present work was easily prepared and found to be stable, has good mechanical strength, sensitive and reusable. In addition, the optode was tested for Al3+ determination in lake water, river water and pharmaceutical samples, which the result was satisfactory.
format Article
author F.B.M, Suah,
M, Ahmad,
L.Y., Heng,
author_facet F.B.M, Suah,
M, Ahmad,
L.Y., Heng,
author_sort F.B.M, Suah,
title A novel polymer inclusion membranes based optode for sensitive determination of Al3+ ions
title_short A novel polymer inclusion membranes based optode for sensitive determination of Al3+ ions
title_full A novel polymer inclusion membranes based optode for sensitive determination of Al3+ ions
title_fullStr A novel polymer inclusion membranes based optode for sensitive determination of Al3+ ions
title_full_unstemmed A novel polymer inclusion membranes based optode for sensitive determination of Al3+ ions
title_sort novel polymer inclusion membranes based optode for sensitive determination of al3+ ions
publisher Elsevier
publishDate 2015
url http://ddms.usim.edu.my/handle/123456789/8493
_version_ 1645152428127944704
score 13.209306