Carbon monoxide reduction in the flue gas during biochar production from oil palm empty fruit bunch
Biomass carbonization technology is implemented to produce charcoal with high-calorific content. However, this technology releases pollutant gases, which adversely affect ambient environment and human health. This study proposed a catalytic gas treatment method using platinum-supported alumina catal...
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Main Authors: | , , , , , , |
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Format: | Article |
Language: | English |
Published: |
Elsevier
2020
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Online Access: | http://psasir.upm.edu.my/id/eprint/88086/1/ABSTRACT.pdf http://psasir.upm.edu.my/id/eprint/88086/ https://www.sciencedirect.com/science/article/pii/S0959652620306272 |
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Summary: | Biomass carbonization technology is implemented to produce charcoal with high-calorific content. However, this technology releases pollutant gases, which adversely affect ambient environment and human health. This study proposed a catalytic gas treatment method using platinum-supported alumina catalyst (Pt/γ-Al2O3) for carbon monoxide emission reduction in oil palm empty fruit bunch carbonization. Carbonization released a rather high carbon monoxide concentration of 5558 ± 53 mg m−3 in the flue gas, exceeding the permissible limit of 1000 mg m−3. At 2.5 wt% of catalyst dosage, the carbon monoxide emission substantially was reduced to 595 ± 9 mg m−3, achieving 89.3% carbon monoxide removal efficiency. This was due to oxidation by the platinum-supported alumina catalyst (Pt/γ-Al2O3), which was done at low temperature, thus transforming carbon monoxide into carbon dioxide. The catalyst demonstrated reusability, attaining >80% carbon monoxide removal efficiency for 5 consecutive carbonization cycles. The biochar produced contained a high energy content of 24.6 ± 0.7 MJ kg−1, which was suitable to be used as a coal substitute. |
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