2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene hydrazinecarbodithioate

The molecules in the crystal structure of the title compound,C19H17N3S2, are linked by an intermolecular N—H N [2.839 (5) A ° ] hydrogen bond via the -N and the pyridyl N atoms. The thione S atom is in a trans position with respect to the methylpyridine fragment across the C—N bond but adopts a cis...

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Main Authors: How, Fiona Ni Foong, Watkin, David J., Crouse, Karen Anne, Mohamed Tahir, Mohamed Ibrahim
格式: Article
语言:English
English
出版: International Union of Crystallography 2007
在线阅读:http://psasir.upm.edu.my/id/eprint/7518/1/2-Naphthylmethyl_N-%5B1-%284-pyridyl%29ethylidene%5D.pdf
http://psasir.upm.edu.my/id/eprint/7518/
http://dx.doi.org/10.1107/S1600536807025652
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总结:The molecules in the crystal structure of the title compound,C19H17N3S2, are linked by an intermolecular N—H N [2.839 (5) A ° ] hydrogen bond via the -N and the pyridyl N atoms. The thione S atom is in a trans position with respect to the methylpyridine fragment across the C—N bond but adopts a cis position with respect to the naphthalene ring across the C—S bond. There is a – stacking interaction between the naphthalene rings, with a centroid–centroid distance of 3.397 (2) A ° .