(E)-4-(Benzyloxy)Benzaldehyde Thiosemicarbazone

In the title compound, C15H15N3OS, the thiosemicarbazone group adopts an E configuration with respect to the C N bond. The benzaldehyde thiosemicarbazone fragment is almost planar [maximum deviation = 0.012 (1) A ° ], while the dihedral angle between the benzyloxy and phenyl rings is 72.48 (5)....

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Main Authors: Tarafder, Md. Tofazzal Hossain, Islam, M. A. A. A. A., Crouse, Karen Anne, Chantrapromma, Suchada, Fun, Hoong Kun
Format: Article
Language:English
English
Published: International Union of Crystallography 2008
Online Access:http://psasir.upm.edu.my/id/eprint/6157/1/63.pdf
http://psasir.upm.edu.my/id/eprint/6157/
http://dx.doi.org/10.1107/S1600536808012671
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spelling my.upm.eprints.61572013-05-27T07:27:35Z http://psasir.upm.edu.my/id/eprint/6157/ (E)-4-(Benzyloxy)Benzaldehyde Thiosemicarbazone Tarafder, Md. Tofazzal Hossain Islam, M. A. A. A. A. Crouse, Karen Anne Chantrapromma, Suchada Fun, Hoong Kun In the title compound, C15H15N3OS, the thiosemicarbazone group adopts an E configuration with respect to the C N bond. The benzaldehyde thiosemicarbazone fragment is almost planar [maximum deviation = 0.012 (1) A ° ], while the dihedral angle between the benzyloxy and phenyl rings is 72.48 (5). In the crystal structure, molecules are interconnected by N—H N and N—H S hydrogen bonds, forming a two-dimensional network parallel to the bc plane and are further stacked along the a axis by – interactions [centroid–centroid separation 3.9043 (7) A ° ]. The crystal structure is also stabilized by C—H interactions International Union of Crystallography 2008 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/6157/1/63.pdf Tarafder, Md. Tofazzal Hossain and Islam, M. A. A. A. A. and Crouse, Karen Anne and Chantrapromma, Suchada and Fun, Hoong Kun (2008) (E)-4-(Benzyloxy)Benzaldehyde Thiosemicarbazone. Acta Crystallographica Section E: Structure Reports Online, 64 (6). pp. 988-989. ISSN 1600-5368 http://dx.doi.org/10.1107/S1600536808012671 10.1107/S1600536808012671 English
institution Universiti Putra Malaysia
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country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
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language English
English
description In the title compound, C15H15N3OS, the thiosemicarbazone group adopts an E configuration with respect to the C N bond. The benzaldehyde thiosemicarbazone fragment is almost planar [maximum deviation = 0.012 (1) A ° ], while the dihedral angle between the benzyloxy and phenyl rings is 72.48 (5). In the crystal structure, molecules are interconnected by N—H N and N—H S hydrogen bonds, forming a two-dimensional network parallel to the bc plane and are further stacked along the a axis by – interactions [centroid–centroid separation 3.9043 (7) A ° ]. The crystal structure is also stabilized by C—H interactions
format Article
author Tarafder, Md. Tofazzal Hossain
Islam, M. A. A. A. A.
Crouse, Karen Anne
Chantrapromma, Suchada
Fun, Hoong Kun
spellingShingle Tarafder, Md. Tofazzal Hossain
Islam, M. A. A. A. A.
Crouse, Karen Anne
Chantrapromma, Suchada
Fun, Hoong Kun
(E)-4-(Benzyloxy)Benzaldehyde Thiosemicarbazone
author_facet Tarafder, Md. Tofazzal Hossain
Islam, M. A. A. A. A.
Crouse, Karen Anne
Chantrapromma, Suchada
Fun, Hoong Kun
author_sort Tarafder, Md. Tofazzal Hossain
title (E)-4-(Benzyloxy)Benzaldehyde Thiosemicarbazone
title_short (E)-4-(Benzyloxy)Benzaldehyde Thiosemicarbazone
title_full (E)-4-(Benzyloxy)Benzaldehyde Thiosemicarbazone
title_fullStr (E)-4-(Benzyloxy)Benzaldehyde Thiosemicarbazone
title_full_unstemmed (E)-4-(Benzyloxy)Benzaldehyde Thiosemicarbazone
title_sort (e)-4-(benzyloxy)benzaldehyde thiosemicarbazone
publisher International Union of Crystallography
publishDate 2008
url http://psasir.upm.edu.my/id/eprint/6157/1/63.pdf
http://psasir.upm.edu.my/id/eprint/6157/
http://dx.doi.org/10.1107/S1600536808012671
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score 13.188475