(E)-4-(Benzyloxy)Benzaldehyde Thiosemicarbazone
In the title compound, C15H15N3OS, the thiosemicarbazone group adopts an E configuration with respect to the C N bond. The benzaldehyde thiosemicarbazone fragment is almost planar [maximum deviation = 0.012 (1) A ° ], while the dihedral angle between the benzyloxy and phenyl rings is 72.48 (5)....
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International Union of Crystallography
2008
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Online Access: | http://psasir.upm.edu.my/id/eprint/6157/1/63.pdf http://psasir.upm.edu.my/id/eprint/6157/ http://dx.doi.org/10.1107/S1600536808012671 |
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my.upm.eprints.61572013-05-27T07:27:35Z http://psasir.upm.edu.my/id/eprint/6157/ (E)-4-(Benzyloxy)Benzaldehyde Thiosemicarbazone Tarafder, Md. Tofazzal Hossain Islam, M. A. A. A. A. Crouse, Karen Anne Chantrapromma, Suchada Fun, Hoong Kun In the title compound, C15H15N3OS, the thiosemicarbazone group adopts an E configuration with respect to the C N bond. The benzaldehyde thiosemicarbazone fragment is almost planar [maximum deviation = 0.012 (1) A ° ], while the dihedral angle between the benzyloxy and phenyl rings is 72.48 (5). In the crystal structure, molecules are interconnected by N—H N and N—H S hydrogen bonds, forming a two-dimensional network parallel to the bc plane and are further stacked along the a axis by – interactions [centroid–centroid separation 3.9043 (7) A ° ]. The crystal structure is also stabilized by C—H interactions International Union of Crystallography 2008 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/6157/1/63.pdf Tarafder, Md. Tofazzal Hossain and Islam, M. A. A. A. A. and Crouse, Karen Anne and Chantrapromma, Suchada and Fun, Hoong Kun (2008) (E)-4-(Benzyloxy)Benzaldehyde Thiosemicarbazone. Acta Crystallographica Section E: Structure Reports Online, 64 (6). pp. 988-989. ISSN 1600-5368 http://dx.doi.org/10.1107/S1600536808012671 10.1107/S1600536808012671 English |
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In the title compound, C15H15N3OS, the thiosemicarbazone
group adopts an E configuration with respect to the C N
bond. The benzaldehyde thiosemicarbazone fragment is
almost planar [maximum deviation = 0.012 (1) A ° ], while the dihedral angle between the benzyloxy and phenyl rings is
72.48 (5). In the crystal structure, molecules are interconnected by N—H N and N—H S hydrogen bonds,
forming a two-dimensional network parallel to the bc plane
and are further stacked along the a axis by – interactions
[centroid–centroid separation 3.9043 (7) A ° ]. The crystal structure is also stabilized by C—H interactions |
format |
Article |
author |
Tarafder, Md. Tofazzal Hossain Islam, M. A. A. A. A. Crouse, Karen Anne Chantrapromma, Suchada Fun, Hoong Kun |
spellingShingle |
Tarafder, Md. Tofazzal Hossain Islam, M. A. A. A. A. Crouse, Karen Anne Chantrapromma, Suchada Fun, Hoong Kun (E)-4-(Benzyloxy)Benzaldehyde Thiosemicarbazone |
author_facet |
Tarafder, Md. Tofazzal Hossain Islam, M. A. A. A. A. Crouse, Karen Anne Chantrapromma, Suchada Fun, Hoong Kun |
author_sort |
Tarafder, Md. Tofazzal Hossain |
title |
(E)-4-(Benzyloxy)Benzaldehyde Thiosemicarbazone |
title_short |
(E)-4-(Benzyloxy)Benzaldehyde Thiosemicarbazone |
title_full |
(E)-4-(Benzyloxy)Benzaldehyde Thiosemicarbazone |
title_fullStr |
(E)-4-(Benzyloxy)Benzaldehyde Thiosemicarbazone |
title_full_unstemmed |
(E)-4-(Benzyloxy)Benzaldehyde Thiosemicarbazone |
title_sort |
(e)-4-(benzyloxy)benzaldehyde thiosemicarbazone |
publisher |
International Union of Crystallography |
publishDate |
2008 |
url |
http://psasir.upm.edu.my/id/eprint/6157/1/63.pdf http://psasir.upm.edu.my/id/eprint/6157/ http://dx.doi.org/10.1107/S1600536808012671 |
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1643823404576407552 |
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13.188475 |