Discrimination of Chiral Guests by Chiral Channels: Variable Temperature Studies by SXRD and Solid State 13C NMR of the Deoxycholic Acid Complexes of Camphorquinone and Endo-3-Bromocamphor
3a,12a-Dihydroxy-5b-cholan-24-oic acid (deoxycholic acid DCA) is able to discriminate between the R- and S-enantiomers of camphorquinone and endo-(1)-3-bromocamphor and select only the S-enantiomers from a racemic mixture. DCA forms novel well ordered 1:1 adducts with (1S)-(1)-camphorquinone and (1S...
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| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English English |
| Published: |
Wiley-Blackwell
2008
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| Online Access: | http://psasir.upm.edu.my/id/eprint/5809/1/Discrimination%20of%20Chiral%20Guests%20by%20Chiral%20Channels.pdf http://psasir.upm.edu.my/id/eprint/5809/ http://dx.doi.org/10.1002/chir.20561 |
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