The importance of Au⋯π(aryl) interactions in the formation of spherical aggregates in binuclear phosphane gold(I) complexes of a bipodal thiocarbamate dianion: a combined crystallographic and computational study, and anti-microbial activity

• Main Authors: Chien, Ing Yeo, Chai, Hoon Khoo, Wern, Cui Chu, Bao, Jing Chen, Pek, Lim Chu, Jiun, Horng Sim, Yoke, Kqueen Cheah, Ahmad, Jimmy, Abdul Halim, Siti Nadiah, Hoi, Ling Seng, Soon, Ng, Roza, A. Otero de la, Tiekink, Edward R. T.
• Format: Article
• Language: English
• Published: Royal Society of Chemistry 2015
• Online Access: http://psasir.upm.edu.my/id/eprint/46624/1/The%20importance%20of%20Au%E2%8B%AF%CF%80%28aryl%29%20interactions%20in%20the%20formation%20of%20spherical%20aggregates%20in%20binuclear%20phosphane%20gold%28I%29%20complexes%20of%20a%20bipodal%20thiocarbamate%20dianion%20a%20combined%20crystallographic%20and%20computational%20study%2C%20and%20anti-micro.pdf; http://psasir.upm.edu.my/id/eprint/46624/; http://pubs.rsc.org/en/journals/journalissues/ra

Binuclear phosphane gold(I) complexes of a bipodal thiocarbamate dianion, (R3PAu)2L, R = Et (1), Ph (2) and Cy (3), where LH2 is {1,4-[MeOC([double bond, length as m-dash]S)N(H)]2C6H4}, have been synthesised, and characterised spectroscopically (NMR and IR) and by X-ray crystallography. The gold ato...