Synthesis of 2-acetyl-5,8-dihydro-1,4-dihydroxy-3-methyl naphthalene: a product from the isomerisation of Diels-Alder adducts of both 5-methyl- and 6-methyl-2-acetyl-1,4-benzoquinone with 1,3-butadiene
2-Acetyl-5,8-dihydro-1,4-dihydroxy-3-methyl-naphthalene was synthesised via Diels-Alder addition of 2-acetyl-3-methyl-1,4-benzoquinone to buta-1,3-diene followed by enolisation. It was identical with material obtained by pyridine-induced acetyl migration from the 1,3-butadiene adducts of both 3- and...
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| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
Taylor & Francis
1996
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| Online Access: | http://psasir.upm.edu.my/id/eprint/42373/1/Synthesis%20of%202-acetyl-5%2C8-dihydro-1%2C4-dihydroxy-3-methyl%20naphthal.pdf http://psasir.upm.edu.my/id/eprint/42373/ http://www.tandfonline.com/doi/abs/10.1080/00397919608003486 |
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