Efficient PPA-SiO2-catalyzed synthesis of β-enaminones under solvent-free conditions

An efficient method has been developed for the synthesis of β-enaminones under solvent-free reaction conditions using PPA-SiO2 as catalyst. The reaction yields were good to excellent (up to 90%). This methodology affords high selectivity and good tolerance of a variety of different functional groups...

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Main Authors: Nisar, Muhammad, Ali, Ihsan, Shah, Muhammad Raza, Qayum, Mughal, Zia-Ul-Haq, Muhammad, Rashid, Umer, Islam, Md. Saiful
Format: Article
Language:English
English
Published: Multidisciplinary Digital Publishing Institute 2013
Online Access:http://psasir.upm.edu.my/id/eprint/30815/1/Efficient%20PPA.pdf
http://psasir.upm.edu.my/id/eprint/30815/
http://www.mdpi.com/1420-3049/18/12
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spelling my.upm.eprints.308152015-12-07T03:28:59Z http://psasir.upm.edu.my/id/eprint/30815/ Efficient PPA-SiO2-catalyzed synthesis of β-enaminones under solvent-free conditions Nisar, Muhammad Ali, Ihsan Shah, Muhammad Raza Qayum, Mughal Zia-Ul-Haq, Muhammad Rashid, Umer Islam, Md. Saiful An efficient method has been developed for the synthesis of β-enaminones under solvent-free reaction conditions using PPA-SiO2 as catalyst. The reaction yields were good to excellent (up to 90%). This methodology affords high selectivity and good tolerance of a variety of different functional groups present on both aromatic and aliphatic amines. In addition, the methodology is environmentally benign and cost-effective due to absence of solvent and easy work-up. Multidisciplinary Digital Publishing Institute 2013-12-10 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/30815/1/Efficient%20PPA.pdf Nisar, Muhammad and Ali, Ihsan and Shah, Muhammad Raza and Qayum, Mughal and Zia-Ul-Haq, Muhammad and Rashid, Umer and Islam, Md. Saiful (2013) Efficient PPA-SiO2-catalyzed synthesis of β-enaminones under solvent-free conditions. Molecules, 2013 (18). pp. 15182-15192. ISSN 1420-3049 http://www.mdpi.com/1420-3049/18/12 10.3390/molecules181215182 English
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
language English
English
description An efficient method has been developed for the synthesis of β-enaminones under solvent-free reaction conditions using PPA-SiO2 as catalyst. The reaction yields were good to excellent (up to 90%). This methodology affords high selectivity and good tolerance of a variety of different functional groups present on both aromatic and aliphatic amines. In addition, the methodology is environmentally benign and cost-effective due to absence of solvent and easy work-up.
format Article
author Nisar, Muhammad
Ali, Ihsan
Shah, Muhammad Raza
Qayum, Mughal
Zia-Ul-Haq, Muhammad
Rashid, Umer
Islam, Md. Saiful
spellingShingle Nisar, Muhammad
Ali, Ihsan
Shah, Muhammad Raza
Qayum, Mughal
Zia-Ul-Haq, Muhammad
Rashid, Umer
Islam, Md. Saiful
Efficient PPA-SiO2-catalyzed synthesis of β-enaminones under solvent-free conditions
author_facet Nisar, Muhammad
Ali, Ihsan
Shah, Muhammad Raza
Qayum, Mughal
Zia-Ul-Haq, Muhammad
Rashid, Umer
Islam, Md. Saiful
author_sort Nisar, Muhammad
title Efficient PPA-SiO2-catalyzed synthesis of β-enaminones under solvent-free conditions
title_short Efficient PPA-SiO2-catalyzed synthesis of β-enaminones under solvent-free conditions
title_full Efficient PPA-SiO2-catalyzed synthesis of β-enaminones under solvent-free conditions
title_fullStr Efficient PPA-SiO2-catalyzed synthesis of β-enaminones under solvent-free conditions
title_full_unstemmed Efficient PPA-SiO2-catalyzed synthesis of β-enaminones under solvent-free conditions
title_sort efficient ppa-sio2-catalyzed synthesis of β-enaminones under solvent-free conditions
publisher Multidisciplinary Digital Publishing Institute
publishDate 2013
url http://psasir.upm.edu.my/id/eprint/30815/1/Efficient%20PPA.pdf
http://psasir.upm.edu.my/id/eprint/30815/
http://www.mdpi.com/1420-3049/18/12
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score 13.211869