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Benzyl N-[(Z)-(1-methyl-2-sulfanyl­propyl­idene)amino]­carbamodithio­ate.

The title compound, C12H16N2S3, was obtained by the condensation reaction of S-benzyl dithio­carbazate and 3-mercaptobutan-2-one. The phenyl ring and thiol (SH) group are approximately perpendicular [S—C—C—C and N—C—C—S torsion angles = 67.8 (3) and 116.9 (2)°, respectively] to the rest of the mol­e...

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Main Authors: Break, Mohammed Khaled, Mehta, Sachin, M. Tahir, M. Ibrahim, Crouse, Karen Anne, Khoo, Teng Jin
Format: Article
Language:English
English
Published: International Union of Crystallography 2013
Online Access:http://psasir.upm.edu.my/id/eprint/30000/1/Benzyl%20N.pdf
http://psasir.upm.edu.my/id/eprint/30000/
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spelling my.upm.eprints.300002015-08-24T06:35:25Z http://psasir.upm.edu.my/id/eprint/30000/ Benzyl N-[(Z)-(1-methyl-2-sulfanyl­propyl­idene)amino]­carbamodithio­ate. Break, Mohammed Khaled Mehta, Sachin M. Tahir, M. Ibrahim Crouse, Karen Anne Khoo, Teng Jin The title compound, C12H16N2S3, was obtained by the condensation reaction of S-benzyl dithio­carbazate and 3-mercaptobutan-2-one. The phenyl ring and thiol (SH) group are approximately perpendicular [S—C—C—C and N—C—C—S torsion angles = 67.8 (3) and 116.9 (2)°, respectively] to the rest of the mol­ecule. In the crystal, mol­ecules are linked by weak S—H(...)S and N—H(...)S hydrogen bonds, π–π inter­actions between the benzene rings [centroid–centroid distance = 3.823 (2) Å] and C—H(...)π inter­actions. International Union of Crystallography 2013 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/30000/1/Benzyl%20N.pdf Break, Mohammed Khaled and Mehta, Sachin and M. Tahir, M. Ibrahim and Crouse, Karen Anne and Khoo, Teng Jin (2013) Benzyl N-[(Z)-(1-methyl-2-sulfanyl­propyl­idene)amino]­carbamodithio­ate. Acta Crystallographica Section E: Structure Reports Online, 69 (pt.2). p. 178. ISSN 1600-5368 10.1107/S1600536812051008 English
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
language English
English
description The title compound, C12H16N2S3, was obtained by the condensation reaction of S-benzyl dithio­carbazate and 3-mercaptobutan-2-one. The phenyl ring and thiol (SH) group are approximately perpendicular [S—C—C—C and N—C—C—S torsion angles = 67.8 (3) and 116.9 (2)°, respectively] to the rest of the mol­ecule. In the crystal, mol­ecules are linked by weak S—H(...)S and N—H(...)S hydrogen bonds, π–π inter­actions between the benzene rings [centroid–centroid distance = 3.823 (2) Å] and C—H(...)π inter­actions.
format Article
author Break, Mohammed Khaled
Mehta, Sachin
M. Tahir, M. Ibrahim
Crouse, Karen Anne
Khoo, Teng Jin
spellingShingle Break, Mohammed Khaled
Mehta, Sachin
M. Tahir, M. Ibrahim
Crouse, Karen Anne
Khoo, Teng Jin
Benzyl N-[(Z)-(1-methyl-2-sulfanyl­propyl­idene)amino]­carbamodithio­ate.
author_facet Break, Mohammed Khaled
Mehta, Sachin
M. Tahir, M. Ibrahim
Crouse, Karen Anne
Khoo, Teng Jin
author_sort Break, Mohammed Khaled
title Benzyl N-[(Z)-(1-methyl-2-sulfanyl­propyl­idene)amino]­carbamodithio­ate.
title_short Benzyl N-[(Z)-(1-methyl-2-sulfanyl­propyl­idene)amino]­carbamodithio­ate.
title_full Benzyl N-[(Z)-(1-methyl-2-sulfanyl­propyl­idene)amino]­carbamodithio­ate.
title_fullStr Benzyl N-[(Z)-(1-methyl-2-sulfanyl­propyl­idene)amino]­carbamodithio­ate.
title_full_unstemmed Benzyl N-[(Z)-(1-methyl-2-sulfanyl­propyl­idene)amino]­carbamodithio­ate.
title_sort benzyl n-[(z)-(1-methyl-2-sulfanyl­propyl­idene)amino]­carbamodithio­ate.
publisher International Union of Crystallography
publishDate 2013
url http://psasir.upm.edu.my/id/eprint/30000/1/Benzyl%20N.pdf
http://psasir.upm.edu.my/id/eprint/30000/
_version_ 1643829927013777408
score 13.2014675

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