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(Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithio­ate.

In the title compound, C16H15N3S2, the central C2N2S2 residue is planar (r.m.s. deviation = 0.045 Å) and the pyridyl and benzene rings are inclined and approximately coplanar to this plane, respectively [dihedral angles = 72.85 (9) and 10.73 (9)°], so that, overall, the mol­ecule adopts an L-shape....

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Main Authors: Low, May Lee, S. A. Ravoof, Thahira Begum, Mohamed Tahir, Mohamed Ibrahim, Crouse, Karen Anne, Tiekink, Edward R. T.
Format: Article
Language:English
English
Published: International Union of Crystallography 2013
Online Access:http://psasir.upm.edu.my/id/eprint/29999/1/Pyridin.pdf
http://psasir.upm.edu.my/id/eprint/29999/
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spelling my.upm.eprints.299992015-10-01T08:33:14Z http://psasir.upm.edu.my/id/eprint/29999/ (Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithio­ate. Low, May Lee S. A. Ravoof, Thahira Begum Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne Tiekink, Edward R. T. In the title compound, C16H15N3S2, the central C2N2S2 residue is planar (r.m.s. deviation = 0.045 Å) and the pyridyl and benzene rings are inclined and approximately coplanar to this plane, respectively [dihedral angles = 72.85 (9) and 10.73 (9)°], so that, overall, the mol­ecule adopts an L-shape. The conformation about each of the N=C [1.290 (3) Å] and C=C [1.340 (3) Å] bonds is E. Supra­molecular chains along [1-10] are stabilized by N—H(...)N(pyridine) hydrogen bonding and these are connected into a double layer that stacks along the c-axis direction by C—H(...)π(pyridine) inter­actions. International Union of Crystallography 2013 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/29999/1/Pyridin.pdf Low, May Lee and S. A. Ravoof, Thahira Begum and Mohamed Tahir, Mohamed Ibrahim and Crouse, Karen Anne and Tiekink, Edward R. T. (2013) (Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithio­ate. Acta Crystallographica Section E: Structure Reports Online, 69 (pt.2). pp. 167-168. ISSN 1600-5368 10.1107/S1600536812051537 English
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
language English
English
description In the title compound, C16H15N3S2, the central C2N2S2 residue is planar (r.m.s. deviation = 0.045 Å) and the pyridyl and benzene rings are inclined and approximately coplanar to this plane, respectively [dihedral angles = 72.85 (9) and 10.73 (9)°], so that, overall, the mol­ecule adopts an L-shape. The conformation about each of the N=C [1.290 (3) Å] and C=C [1.340 (3) Å] bonds is E. Supra­molecular chains along [1-10] are stabilized by N—H(...)N(pyridine) hydrogen bonding and these are connected into a double layer that stacks along the c-axis direction by C—H(...)π(pyridine) inter­actions.
format Article
author Low, May Lee
S. A. Ravoof, Thahira Begum
Mohamed Tahir, Mohamed Ibrahim
Crouse, Karen Anne
Tiekink, Edward R. T.
spellingShingle Low, May Lee
S. A. Ravoof, Thahira Begum
Mohamed Tahir, Mohamed Ibrahim
Crouse, Karen Anne
Tiekink, Edward R. T.
(Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithio­ate.
author_facet Low, May Lee
S. A. Ravoof, Thahira Begum
Mohamed Tahir, Mohamed Ibrahim
Crouse, Karen Anne
Tiekink, Edward R. T.
author_sort Low, May Lee
title (Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithio­ate.
title_short (Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithio­ate.
title_full (Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithio­ate.
title_fullStr (Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithio­ate.
title_full_unstemmed (Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithio­ate.
title_sort (pyridin-4-yl)methyl n′-(3-phenylallylidene)hydrazinecarbodithio­ate.
publisher International Union of Crystallography
publishDate 2013
url http://psasir.upm.edu.my/id/eprint/29999/1/Pyridin.pdf
http://psasir.upm.edu.my/id/eprint/29999/
_version_ 1643829926719127552
score 13.2014675

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