Transesterification reaction optimization and evaluation of biodiesel produced from seed oil of Colocynthis citrullus L.

This work presents Colocynthis citrullus L. (egusi) seed oil as a potential feedstock for biodiesel production. The transesterification process was optimized using response surface methodology (RSM) with three-level-three-factors face-centered central composite design employed. Catalyst (NaOH) amoun...

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Bibliographic Details
Main Authors: Giwa, Solomon O., Abdullah, Luqman Chuah, Adam, Nor Mariah
Format: Article
Language:English
Published: American V - King Scientific Publishing 2014
Online Access:http://psasir.upm.edu.my/id/eprint/28870/1/Transesterification%20reaction%20optimization%20and%20evaluation%20of%20biodiesel%20produced%20from%20seed%20oil%20of%20Colocynthis%20citrullus%20L.pdf
http://psasir.upm.edu.my/id/eprint/28870/
http://www.vkingpub.com/VkAdmin/Ll/LL.DE.asp?action=Paper_Information&id=175&at=Transesterification+Reaction+Optimization+and+Evaluation+of+Biodiesel+Produced+From+Seed+Oil+of+Colocynthis+Citrullus+L.&jn=Current%20Advances%20in%20Energy%20Research#sthash.
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Summary:This work presents Colocynthis citrullus L. (egusi) seed oil as a potential feedstock for biodiesel production. The transesterification process was optimized using response surface methodology (RSM) with three-level-three-factors face-centered central composite design employed. Catalyst (NaOH) amount (0.25-1.8% (w/w), reaction temperature (45-65 °C) and oil-methanol molar ratio (4-10) were studied as important factors influencing the reaction. The optimum values (1:6.54 oil/methanol molar ratio, 1.22% (w/w) catalyst amount, and 65 ºC reaction temperature) predicted by the mathematical model generated using RSM gave ester yield of 84.46%, under experimental conditions. The fuel properties of egusi oil methyl ester (EOME) measured satisfied both ASTM D6751 and EN 14214 biodiesel standards with a kinematic viscosity of 3.87 mm2/s. Fatty acid profile and fuel properties of EOME were found similar to those of soybean, safflower and sunflower biodiesel.