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Bis{S-benzyl 3-[(phenyl)(pyridin-2-yl)- methylidene]dithiocarbazato}zinc acetonitrile monosolvate.

In the title compound, [Zn(C20H16N3S2)2]·CH3CN, two different Schiff base moieties coordinate to the central ZnII ion as tridentate N,N′,S-chelating ligands, creating a distorted octa­hedral environment [the smallest angle being 73.24 (6)° and the widest angle being 155.73 (7)°], with the two S atom...

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Main Authors: Begum, Thahira, Omar, Siti Aminah, Mohamed Tahir, Mohamed Ibrahim, Crouse, Karen Anne
Format: Article
Language:English
Published: International Union of Crystallography 2012
Online Access:http://psasir.upm.edu.my/id/eprint/25231/
http://www.iucr.org/
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spelling my.upm.eprints.252312013-10-31T01:50:13Z http://psasir.upm.edu.my/id/eprint/25231/ Bis{S-benzyl 3-[(phenyl)(pyridin-2-yl)- methylidene]dithiocarbazato}zinc acetonitrile monosolvate. Begum, Thahira Omar, Siti Aminah Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne In the title compound, [Zn(C20H16N3S2)2]·CH3CN, two different Schiff base moieties coordinate to the central ZnII ion as tridentate N,N′,S-chelating ligands, creating a distorted octa­hedral environment [the smallest angle being 73.24 (6)° and the widest angle being 155.73 (7)°], with the two S atoms in cis positions. The dihedral angle between the mean planes of the two coordinating ligands is 83.65 (5)°. The crystal packing is consolidated by weak C—H(...)N hydrogen-bonding inter­actions. International Union of Crystallography 2012 Article PeerReviewed Begum, Thahira and Omar, Siti Aminah and Mohamed Tahir, Mohamed Ibrahim and Crouse, Karen Anne (2012) Bis{S-benzyl 3-[(phenyl)(pyridin-2-yl)- methylidene]dithiocarbazato}zinc acetonitrile monosolvate. Acta Crystallographica Section E: Structure Reports Online, E68 (4). pp. 390-391. ISSN 1600-5368 http://www.iucr.org/ 10.1107/S1600536812009592 English
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
language English
description In the title compound, [Zn(C20H16N3S2)2]·CH3CN, two different Schiff base moieties coordinate to the central ZnII ion as tridentate N,N′,S-chelating ligands, creating a distorted octa­hedral environment [the smallest angle being 73.24 (6)° and the widest angle being 155.73 (7)°], with the two S atoms in cis positions. The dihedral angle between the mean planes of the two coordinating ligands is 83.65 (5)°. The crystal packing is consolidated by weak C—H(...)N hydrogen-bonding inter­actions.
format Article
author Begum, Thahira
Omar, Siti Aminah
Mohamed Tahir, Mohamed Ibrahim
Crouse, Karen Anne
spellingShingle Begum, Thahira
Omar, Siti Aminah
Mohamed Tahir, Mohamed Ibrahim
Crouse, Karen Anne
Bis{S-benzyl 3-[(phenyl)(pyridin-2-yl)- methylidene]dithiocarbazato}zinc acetonitrile monosolvate.
author_facet Begum, Thahira
Omar, Siti Aminah
Mohamed Tahir, Mohamed Ibrahim
Crouse, Karen Anne
author_sort Begum, Thahira
title Bis{S-benzyl 3-[(phenyl)(pyridin-2-yl)- methylidene]dithiocarbazato}zinc acetonitrile monosolvate.
title_short Bis{S-benzyl 3-[(phenyl)(pyridin-2-yl)- methylidene]dithiocarbazato}zinc acetonitrile monosolvate.
title_full Bis{S-benzyl 3-[(phenyl)(pyridin-2-yl)- methylidene]dithiocarbazato}zinc acetonitrile monosolvate.
title_fullStr Bis{S-benzyl 3-[(phenyl)(pyridin-2-yl)- methylidene]dithiocarbazato}zinc acetonitrile monosolvate.
title_full_unstemmed Bis{S-benzyl 3-[(phenyl)(pyridin-2-yl)- methylidene]dithiocarbazato}zinc acetonitrile monosolvate.
title_sort bis{s-benzyl 3-[(phenyl)(pyridin-2-yl)- methylidene]dithiocarbazato}zinc acetonitrile monosolvate.
publisher International Union of Crystallography
publishDate 2012
url http://psasir.upm.edu.my/id/eprint/25231/
http://www.iucr.org/
_version_ 1643828598718595072
score 13.160551

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