Benzyl N-[1-(thio­phen-2-yl)ethyl­idene)]-hydrazinecarbodi­thioate

• Main Authors: Chan, Eddy Mun Hoe, Crouse, Karen Anne, Tarafder, M. Tofazzal H., Mohd Yamin, Bohari
• Format: Article
• Language: English
• Published: International Union of Crystallography 2003
• Online Access: http://psasir.upm.edu.my/id/eprint/25098/1/Benzyl%20N-%5B1-%28thiophen-2-yl%29ethylidene%5D-hydrazinecarbodithioate.pdf; http://psasir.upm.edu.my/id/eprint/25098/; http://scripts.iucr.org/cgi-bin/paper?S1600536803007517

In the title compound, C14H14N2S3, the benzyl and 1-(thiophen-2-yl)ethylideneamine groups are cis and trans to the thiono S atom across the C-S and C-N bonds, respectively. The dithiocarbazate plane makes dihedral angles of 9.14 (6) and 85.40 (8)° with the thiophenemethyleneamine and benzyl fragments, respectively. In the crystal structure, the molecules are linked by N-H...S hydrogen bonds between the amino group and the thiono S atoms and are arranged as dimers parallel to ab face.