Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride.
The title compound, [C7H10N3S2]+·Cl-, exists as an ionic compound of a dithiocarbazate system, with a zwitterionic +H3NNCS- moiety and a protonated pyridine ring. The C-S thione bond distance of the zwitterionic moiety [1.708 (2) Å] is longer than the normal double bond and the C-N of the carbazate...
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International Union of Crystallography
2003
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Online Access: | http://psasir.upm.edu.my/id/eprint/25097/1/Hydrazine%20carbodithioic%20acid%20pyridinium.pdf http://psasir.upm.edu.my/id/eprint/25097/ http://www.iucr.org/ |
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my.upm.eprints.250972015-11-27T02:29:33Z http://psasir.upm.edu.my/id/eprint/25097/ Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride. Crouse, Karen Anne Kar , Teng Chew Yamin, Bohari M. Seik, Weng Ng Tarafder, M.T.H. The title compound, [C7H10N3S2]+·Cl-, exists as an ionic compound of a dithiocarbazate system, with a zwitterionic +H3NNCS- moiety and a protonated pyridine ring. The C-S thione bond distance of the zwitterionic moiety [1.708 (2) Å] is longer than the normal double bond and the C-N of the carbazate moiety has double-bond character. The crystal packing is stabilized by intramolecular hydrogen bonds, which form a two-dimensional network perpendicular to b. International Union of Crystallography 2003-02 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/25097/1/Hydrazine%20carbodithioic%20acid%20pyridinium.pdf Crouse, Karen Anne and Kar , Teng Chew and Yamin, Bohari M. and Seik, Weng Ng and Tarafder, M.T.H. (2003) Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride. Acta Crystallographica Section E: Structure Reports Online, 59 (2). o148-o150. ISSN 1600-5368 http://www.iucr.org/ 10.1107/S160053680300014X English |
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The title compound, [C7H10N3S2]+·Cl-, exists as an ionic compound of a dithiocarbazate system, with a zwitterionic +H3NNCS- moiety and a protonated pyridine ring. The C-S thione bond distance of the zwitterionic moiety [1.708 (2) Å] is longer than the normal double bond and the C-N of the carbazate moiety has double-bond character. The crystal packing is stabilized by intramolecular hydrogen bonds, which form a two-dimensional network perpendicular to b. |
format |
Article |
author |
Crouse, Karen Anne Kar , Teng Chew Yamin, Bohari M. Seik, Weng Ng Tarafder, M.T.H. |
spellingShingle |
Crouse, Karen Anne Kar , Teng Chew Yamin, Bohari M. Seik, Weng Ng Tarafder, M.T.H. Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride. |
author_facet |
Crouse, Karen Anne Kar , Teng Chew Yamin, Bohari M. Seik, Weng Ng Tarafder, M.T.H. |
author_sort |
Crouse, Karen Anne |
title |
Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride. |
title_short |
Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride. |
title_full |
Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride. |
title_fullStr |
Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride. |
title_full_unstemmed |
Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride. |
title_sort |
hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride. |
publisher |
International Union of Crystallography |
publishDate |
2003 |
url |
http://psasir.upm.edu.my/id/eprint/25097/1/Hydrazine%20carbodithioic%20acid%20pyridinium.pdf http://psasir.upm.edu.my/id/eprint/25097/ http://www.iucr.org/ |
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1643828558102003712 |
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13.159267 |