Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride.

The title compound, [C7H10N3S2]+·Cl-, exists as an ionic compound of a dithiocarbazate system, with a zwitterionic +H3NNCS- moiety and a protonated pyridine ring. The C-S thione bond distance of the zwitterionic moiety [1.708 (2) Å] is longer than the normal double bond and the C-N of the carbazate...

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Main Authors: Crouse, Karen Anne, Kar , Teng Chew, Yamin, Bohari M., Seik, Weng Ng, Tarafder, M.T.H.
Format: Article
Language:English
English
Published: International Union of Crystallography 2003
Online Access:http://psasir.upm.edu.my/id/eprint/25097/1/Hydrazine%20carbodithioic%20acid%20pyridinium.pdf
http://psasir.upm.edu.my/id/eprint/25097/
http://www.iucr.org/
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spelling my.upm.eprints.250972015-11-27T02:29:33Z http://psasir.upm.edu.my/id/eprint/25097/ Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride. Crouse, Karen Anne Kar , Teng Chew Yamin, Bohari M. Seik, Weng Ng Tarafder, M.T.H. The title compound, [C7H10N3S2]+·Cl-, exists as an ionic compound of a dithiocarbazate system, with a zwitterionic +H3NNCS- moiety and a protonated pyridine ring. The C-S thione bond distance of the zwitterionic moiety [1.708 (2) Å] is longer than the normal double bond and the C-N of the carbazate moiety has double-bond character. The crystal packing is stabilized by intramolecular hydrogen bonds, which form a two-dimensional network perpendicular to b. International Union of Crystallography 2003-02 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/25097/1/Hydrazine%20carbodithioic%20acid%20pyridinium.pdf Crouse, Karen Anne and Kar , Teng Chew and Yamin, Bohari M. and Seik, Weng Ng and Tarafder, M.T.H. (2003) Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride. Acta Crystallographica Section E: Structure Reports Online, 59 (2). o148-o150. ISSN 1600-5368 http://www.iucr.org/ 10.1107/S160053680300014X English
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
language English
English
description The title compound, [C7H10N3S2]+·Cl-, exists as an ionic compound of a dithiocarbazate system, with a zwitterionic +H3NNCS- moiety and a protonated pyridine ring. The C-S thione bond distance of the zwitterionic moiety [1.708 (2) Å] is longer than the normal double bond and the C-N of the carbazate moiety has double-bond character. The crystal packing is stabilized by intramolecular hydrogen bonds, which form a two-dimensional network perpendicular to b.
format Article
author Crouse, Karen Anne
Kar , Teng Chew
Yamin, Bohari M.
Seik, Weng Ng
Tarafder, M.T.H.
spellingShingle Crouse, Karen Anne
Kar , Teng Chew
Yamin, Bohari M.
Seik, Weng Ng
Tarafder, M.T.H.
Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride.
author_facet Crouse, Karen Anne
Kar , Teng Chew
Yamin, Bohari M.
Seik, Weng Ng
Tarafder, M.T.H.
author_sort Crouse, Karen Anne
title Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride.
title_short Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride.
title_full Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride.
title_fullStr Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride.
title_full_unstemmed Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride.
title_sort hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride.
publisher International Union of Crystallography
publishDate 2003
url http://psasir.upm.edu.my/id/eprint/25097/1/Hydrazine%20carbodithioic%20acid%20pyridinium.pdf
http://psasir.upm.edu.my/id/eprint/25097/
http://www.iucr.org/
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score 13.159267