2-Naphthylmethyl N-(3-pyridylmethylene) hydrazinecarbodithioate.
The title molecule, C18H15N3S2, is a trans-cis conformer. The thione S atom is in a trans configuration with respect to the pyridine ring but adopts a cis configuration with respect to the napthylmethyl substituent. In the crystal structure, molecules are linked by intermolecular N-H...N hydrogen bo...
Saved in:
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English English |
| Published: |
International Union of Crystallography
2007
|
| Online Access: | http://psasir.upm.edu.my/id/eprint/24955/1/2%20Naphthylmethyl.pdf http://psasir.upm.edu.my/id/eprint/24955/ http://www.iucr.org/ |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Summary: | The title molecule, C18H15N3S2, is a trans-cis conformer. The thione S atom is in a trans configuration with respect to the pyridine ring but adopts a cis configuration with respect to the napthylmethyl substituent. In the crystal structure, molecules are linked by intermolecular N-H...N hydrogen bonds via[alpha]-N donor atoms and pyridyl N acceptor atoms into one-dimensional chains along the a axis. In addition, pairs of inversion-related dithiocarbazate groups and the attached pyridine groups are arranged with an interplanar distance 3.30 Å, leading to [pi]-[pi] stacking interactions. The crystal used for the structure determination was twinned.
|
|---|