2-Naphthylmethyl N-(3-pyridylmethylene) hydrazinecarbodithioate.
The title molecule, C18H15N3S2, is a trans-cis conformer. The thione S atom is in a trans configuration with respect to the pyridine ring but adopts a cis configuration with respect to the napthylmethyl substituent. In the crystal structure, molecules are linked by intermolecular N-H...N hydrogen bo...
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| المؤلفون الرئيسيون: | , , , |
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| التنسيق: | مقال |
| اللغة: | English English |
| منشور في: |
International Union of Crystallography
2007
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| الوصول للمادة أونلاين: | http://psasir.upm.edu.my/id/eprint/24955/1/2%20Naphthylmethyl.pdf http://psasir.upm.edu.my/id/eprint/24955/ http://www.iucr.org/ |
| الوسوم: |
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| الملخص: | The title molecule, C18H15N3S2, is a trans-cis conformer. The thione S atom is in a trans configuration with respect to the pyridine ring but adopts a cis configuration with respect to the napthylmethyl substituent. In the crystal structure, molecules are linked by intermolecular N-H...N hydrogen bonds via[alpha]-N donor atoms and pyridyl N acceptor atoms into one-dimensional chains along the a axis. In addition, pairs of inversion-related dithiocarbazate groups and the attached pyridine groups are arranged with an interplanar distance 3.30 Å, leading to [pi]-[pi] stacking interactions. The crystal used for the structure determination was twinned.
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