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(2,2'-Bipyridyl-[kappa]2N,N')bis(N-butyl-N-methyldithiocarbamato-[kappa]2S,S')cadmium(II).

The CdII atom in the title compound, [Cd(C6H12NS2)2(C10H8N2)], is hexacoordinated by two dithiocarbamate ligands and the N atoms from a bidentate 2,2'-bipyridyl molecule. The coordination geometry is based on a distorted trigonal-prismatic arrangement of the N2S4 donor set. Supramolecular chain...

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Main Authors: Jamaluddin, Nur Amirah, Baba, Ibrahim, Mohamed Tahir, Mohamed Ibrahim, Tiekink, Edward R. T.
Format: Article
Language:English
English
Published: International Union of Crystallography 2011
Online Access:http://psasir.upm.edu.my/id/eprint/24787/1/2.pdf
http://psasir.upm.edu.my/id/eprint/24787/
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spelling my.upm.eprints.247872015-10-06T04:07:38Z http://psasir.upm.edu.my/id/eprint/24787/ (2,2'-Bipyridyl-[kappa]2N,N')bis(N-butyl-N-methyldithiocarbamato-[kappa]2S,S')cadmium(II). Jamaluddin, Nur Amirah Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. The CdII atom in the title compound, [Cd(C6H12NS2)2(C10H8N2)], is hexacoordinated by two dithiocarbamate ligands and the N atoms from a bidentate 2,2'-bipyridyl molecule. The coordination geometry is based on a distorted trigonal-prismatic arrangement of the N2S4 donor set. Supramolecular chains, aligned along the a-axis direction, are mediated by C-H...S interactions and these are connected into layers that stack along the c axis via [pi]-[pi] interactions [Cg(pyridyl)...Cg(pyridyl) = 3.6587 (13) Å]. International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/24787/1/2.pdf Jamaluddin, Nur Amirah and Baba, Ibrahim and Mohamed Tahir, Mohamed Ibrahim and Tiekink, Edward R. T. (2011) (2,2'-Bipyridyl-[kappa]2N,N')bis(N-butyl-N-methyldithiocarbamato-[kappa]2S,S')cadmium(II). Acta Crystallographica Section E: Structure Reports Online, 67. pp. 384-385. ISSN 1600-5368 10.1107/S1600536811006878 English
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
language English
English
description The CdII atom in the title compound, [Cd(C6H12NS2)2(C10H8N2)], is hexacoordinated by two dithiocarbamate ligands and the N atoms from a bidentate 2,2'-bipyridyl molecule. The coordination geometry is based on a distorted trigonal-prismatic arrangement of the N2S4 donor set. Supramolecular chains, aligned along the a-axis direction, are mediated by C-H...S interactions and these are connected into layers that stack along the c axis via [pi]-[pi] interactions [Cg(pyridyl)...Cg(pyridyl) = 3.6587 (13) Å].
format Article
author Jamaluddin, Nur Amirah
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
spellingShingle Jamaluddin, Nur Amirah
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
(2,2'-Bipyridyl-[kappa]2N,N')bis(N-butyl-N-methyldithiocarbamato-[kappa]2S,S')cadmium(II).
author_facet Jamaluddin, Nur Amirah
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
author_sort Jamaluddin, Nur Amirah
title (2,2'-Bipyridyl-[kappa]2N,N')bis(N-butyl-N-methyldithiocarbamato-[kappa]2S,S')cadmium(II).
title_short (2,2'-Bipyridyl-[kappa]2N,N')bis(N-butyl-N-methyldithiocarbamato-[kappa]2S,S')cadmium(II).
title_full (2,2'-Bipyridyl-[kappa]2N,N')bis(N-butyl-N-methyldithiocarbamato-[kappa]2S,S')cadmium(II).
title_fullStr (2,2'-Bipyridyl-[kappa]2N,N')bis(N-butyl-N-methyldithiocarbamato-[kappa]2S,S')cadmium(II).
title_full_unstemmed (2,2'-Bipyridyl-[kappa]2N,N')bis(N-butyl-N-methyldithiocarbamato-[kappa]2S,S')cadmium(II).
title_sort (2,2'-bipyridyl-[kappa]2n,n')bis(n-butyl-n-methyldithiocarbamato-[kappa]2s,s')cadmium(ii).
publisher International Union of Crystallography
publishDate 2011
url http://psasir.upm.edu.my/id/eprint/24787/1/2.pdf
http://psasir.upm.edu.my/id/eprint/24787/
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score 13.209306

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