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Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc

The ZnII atom in the title compound, [Zn(C5H10NS2)2(C12H8N2)], exists in a distorted cis-octahedral N2S4 donor set defined by two chelating dithiocarbamate anions as well as a 1,10-phenanthroline ligand. Each of the ligands coordinates in a symmetric mode. The crystal packing is stabilized by weak...

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Main Authors: Abdul Wahab, Nor Asiken, Baba, Ibrahim, Mohamed Tahir, Mohamed Ibrahim, Tiekink, Edward R. T.
Format: Article
Language:English
Published: International Union of Crystallography 2011
Online Access:http://psasir.upm.edu.my/id/eprint/24786/1/Bis.pdf
http://psasir.upm.edu.my/id/eprint/24786/
http://dx.doi.org/10.1107/S1600536811012499
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spelling my.upm.eprints.247862016-02-10T06:06:14Z http://psasir.upm.edu.my/id/eprint/24786/ Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc Abdul Wahab, Nor Asiken Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. The ZnII atom in the title compound, [Zn(C5H10NS2)2(C12H8N2)], exists in a distorted cis-octahedral N2S4 donor set defined by two chelating dithiocarbamate anions as well as a 1,10-phenanthroline ligand. Each of the ligands coordinates in a symmetric mode. The crystal packing is stabilized by weak C-H...S, C-H...[pi](ZnS2C) and [pi]-[pi] [ring centroid distance between centrosymmetrically related pyridyl rings = 3.5955 (13) Å] interactions International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/24786/1/Bis.pdf Abdul Wahab, Nor Asiken and Baba, Ibrahim and Mohamed Tahir, Mohamed Ibrahim and Tiekink, Edward R. T. (2011) Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc. Acta Crystallographica Section E: Structure Reports Online, 67 (7). pp. 553-554. ISSN 1600-5368 http://dx.doi.org/10.1107/S1600536811012499 10.1107/S1600536811012499
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
language English
description The ZnII atom in the title compound, [Zn(C5H10NS2)2(C12H8N2)], exists in a distorted cis-octahedral N2S4 donor set defined by two chelating dithiocarbamate anions as well as a 1,10-phenanthroline ligand. Each of the ligands coordinates in a symmetric mode. The crystal packing is stabilized by weak C-H...S, C-H...[pi](ZnS2C) and [pi]-[pi] [ring centroid distance between centrosymmetrically related pyridyl rings = 3.5955 (13) Å] interactions
format Article
author Abdul Wahab, Nor Asiken
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
spellingShingle Abdul Wahab, Nor Asiken
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc
author_facet Abdul Wahab, Nor Asiken
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
author_sort Abdul Wahab, Nor Asiken
title Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc
title_short Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc
title_full Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc
title_fullStr Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc
title_full_unstemmed Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc
title_sort bis(n-isopropyl-n-methyldithiocarbamato-[kappa]2s,s')(1,10-phenanthroline-[kappa]2n,n')zinc
publisher International Union of Crystallography
publishDate 2011
url http://psasir.upm.edu.my/id/eprint/24786/1/Bis.pdf
http://psasir.upm.edu.my/id/eprint/24786/
http://dx.doi.org/10.1107/S1600536811012499
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score 13.18916

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