(N-Benzyl-N-ethyldithiocarbamato)di-tert-butylchloridotin(IV).
The SnIV atom in the title diorganotin dithiocarbamate, [Sn(C4H9)2Cl(C10H12NS2)], is pentacoordinated by an asymmetrically coordinating dithiocarbamate ligand, a Cl and two C atoms of the Sn-bound tert-butyl groups. The resulting C2ClS2 donor set defines a coordination geometry intermediate between...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English English |
| Published: |
International Union of Crystallography
2011
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| Online Access: | http://psasir.upm.edu.my/id/eprint/24785/1/N-benzyl-N.pdf http://psasir.upm.edu.my/id/eprint/24785/ |
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| Summary: | The SnIV atom in the title diorganotin dithiocarbamate, [Sn(C4H9)2Cl(C10H12NS2)], is pentacoordinated by an asymmetrically coordinating dithiocarbamate ligand, a Cl and two C atoms of the Sn-bound tert-butyl groups. The resulting C2ClS2 donor set defines a coordination geometry intermediate between square pyramidal and trigonal bipyramidal with a slight tendency towards the former. In the crystal structure, C-H...[pi] contacts link centrosymmetrically related molecules into dimeric aggregates. |
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