Preparation and properties of natural rubber/layered double hydroxide nanocomposites

• Main Authors: Abdullah, Mohd Aidil Adhha, Ahmad @ Ayob, Mansor, Wan Yunus, Wan Md. Zin, Ab. Rahman, Mohamad Zaki, Hussein, Mohd Zobir, Mohd Dahlan, Khairul Zaman
• Format: Article
• Language: English
• Published: UMT Publisher 2010
• Online Access: http://psasir.upm.edu.my/id/eprint/16315/1/Preparation%20and%20properties%20of%20natural%20rubber.pdf; http://psasir.upm.edu.my/id/eprint/16315/; http://jssm.umt.edu.my/files/2012/05/5.Dec10.pdf

Nanocomposites of natural rubber (NR)/organo ZnAl layered double hydroxide (ZnAl LDH-DS) were successfully synthesized and characterized. A hydrophilic Zn-Al layered double hydroxide (ZnAl LDH-NO3-) was converted into the organophilic form by replacing the nitrate ion in between the ZnAl LDH-NO3- with dodecylsulfate ion (DS) to form ZnAl LDH-DS. The melt intercalation technique followed by vulcanization process was adopted to synthesize the nanocomposites of NR/ZnAl LDH-DS. Intercalation of DS ion into the interlayer of ZnAl LDH-NO3- increased the surface area and the porosity of the LDH. X-Ray diffractogram of the organophilic ZnAl LDH-DS shows that the basal spacing of the ZnAl LDH-NO3- expands from 0.89 to 2.53 nm due to the accommodation of DS ion in the intergallery. After the compounding process with the NR, the basal spacing of ZnAl LDH-DS in the composites is increased to 3.90 and 3.27 nm when the ZnAl LDH-DS contents were 1 and 15 phr, respectively. Transmission electron microscope image revealed that the ZnAl LDH-DS was distributed in the NR matrix in such a way of exfoliated and different grade of intercalated. The tensile strength values of NR/ ZnAl LDH-DS (nanocomposites) were found to be higher than that of the NR/ZnAl LDH-NO3- (macrocomposites).