Solid-State P NMR, Far-IR, and Structural Studies on Two-Coordinate (Tris(2,4,6-trimethoxyphenyl)phosphine)copper(I) Chloride and Bromide

• Main Authors: Bowmaker, Graham A., Cotton, John D., Healy, Peter C., Kildea, John D.
• Format: Article
• Published: American Chemical Society 1989
• Online Access: http://psasir.upm.edu.my/id/eprint/114452/; https://pubs.acs.org/doi/abs/10.1021/ic00307a009

The reactions of acetonitrile solutions of copper(I) chloride, CuCl, and copper(I) bromide, CuBr, with the sterically hindered, highly basic tertiary phosphine ligand tris(2,4,6-trimethoxyphenyl)phosphine [=P(2,4,6)3] have been shown to form 1:1 monomeric adducts, [P(2,4,6)3 cux],The two compounds a...