Thermal and degradation analysis of electrospun polyurethane prepared using radiation induced grafting
Polyurethane (PU) membranes was prepared using electrospinning followed by modification with 2-hydroxyethyl methacrylate (HEMA) by radiation-induced grafting (RIG) copolymerization method via electron beam. The lack of knowledge of polymer properties of PU-based membrane prepared using RIG method ne...
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Semarak Ilmu Publishing
2023
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my.upm.eprints.1101282024-09-04T04:26:48Z http://psasir.upm.edu.my/id/eprint/110128/ Thermal and degradation analysis of electrospun polyurethane prepared using radiation induced grafting Ahmad Tarmizi, Zatil Izzah Rasit Ali, Roshafima Nasef, Mohamed Mahmoud Mohamed Radzi, Afifah Mardhiah Md Akim, Abdah Eshak, Zolkapli Md Noor, Sabariah Shafie, Nur Fathin Amirah Mohd Faizo, Syazwani Polyurethane (PU) membranes was prepared using electrospinning followed by modification with 2-hydroxyethyl methacrylate (HEMA) by radiation-induced grafting (RIG) copolymerization method via electron beam. The lack of knowledge of polymer properties of PU-based membrane prepared using RIG method need for dedicated study. Thus, the effect of thermal stability, in vitro degradation, water uptake analysis, and surface morphology after 84 days’ incubation times toward grafted PU-g-poly(HEMA) membrane was evaluated for the first time using thermal gravimetric analysis (TGA), analysis of mass, percentage of water uptake and Scanning Electron Microscope (SEM), respectively. Based on the DTGA curves, the electrospun PU exhibits two-stage of deposition. After grafted with HEMA, the first stage of decomposition was shifted to the lower temperature, and the second stage of decomposition was shifted to a higher temperature. At 500 °C, PU grafted with HEMA leaves residue about 3.526 more elevated in value than original material of PU, which is 1.151. Degradation test showed that a higher percentage degree of grafting was lowering the percentage of weight loss. SEM images supported the morphology observation shows no noticeable changes such as cracked or eroded has occurred. In conclusion, electrospun PU grafted with HEMA was improved its thermal stability, stable in swelling properties and was found competent to degrade slowly in phosphate buffer saline (PBS). The results show that PU-g-poly(HEMA) exhibits better thermal stability than pure poly(HEMA) and the amorphous regions give the polymer toughness and could be up-and coming candidates for tissue engineering including artificial blood contracting medical devices. Semarak Ilmu Publishing 2023 Article PeerReviewed Ahmad Tarmizi, Zatil Izzah and Rasit Ali, Roshafima and Nasef, Mohamed Mahmoud and Mohamed Radzi, Afifah Mardhiah and Md Akim, Abdah and Eshak, Zolkapli and Md Noor, Sabariah and Shafie, Nur Fathin Amirah and Mohd Faizo, Syazwani (2023) Thermal and degradation analysis of electrospun polyurethane prepared using radiation induced grafting. Journal of Advanced Research in Fluid Mechanics and Thermal Sciences, 108 (2). 110 - 121. ISSN 2289-7879 https://semarakilmu.com.my/journals/index.php/fluid_mechanics_thermal_sciences/article/view/1520 10.37934/arfmts.108.2.110121 |
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Polyurethane (PU) membranes was prepared using electrospinning followed by modification with 2-hydroxyethyl methacrylate (HEMA) by radiation-induced grafting (RIG) copolymerization method via electron beam. The lack of knowledge of polymer properties of PU-based membrane prepared using RIG method need for dedicated study. Thus, the effect of thermal stability, in vitro degradation, water uptake analysis, and surface morphology after 84 days’ incubation times toward grafted PU-g-poly(HEMA) membrane was evaluated for the first time using thermal gravimetric analysis (TGA), analysis of mass, percentage of water uptake and Scanning Electron Microscope (SEM), respectively. Based on the DTGA curves, the electrospun PU exhibits two-stage of deposition. After grafted with HEMA, the first stage of decomposition was shifted to the lower temperature, and the second stage of decomposition was shifted to a higher temperature. At 500 °C, PU grafted with HEMA leaves residue about 3.526 more elevated in value than original material of PU, which is 1.151. Degradation test showed that a higher percentage degree of grafting was lowering the percentage of weight loss. SEM images supported the morphology observation shows no noticeable changes such as cracked or eroded has occurred. In conclusion, electrospun PU grafted with HEMA was improved its thermal stability, stable in swelling properties and was found competent to degrade slowly in phosphate buffer saline (PBS). The results show that PU-g-poly(HEMA) exhibits better thermal stability than pure poly(HEMA) and the amorphous regions give the polymer toughness and could be up-and coming candidates for tissue engineering including artificial blood contracting medical devices. |
format |
Article |
author |
Ahmad Tarmizi, Zatil Izzah Rasit Ali, Roshafima Nasef, Mohamed Mahmoud Mohamed Radzi, Afifah Mardhiah Md Akim, Abdah Eshak, Zolkapli Md Noor, Sabariah Shafie, Nur Fathin Amirah Mohd Faizo, Syazwani |
spellingShingle |
Ahmad Tarmizi, Zatil Izzah Rasit Ali, Roshafima Nasef, Mohamed Mahmoud Mohamed Radzi, Afifah Mardhiah Md Akim, Abdah Eshak, Zolkapli Md Noor, Sabariah Shafie, Nur Fathin Amirah Mohd Faizo, Syazwani Thermal and degradation analysis of electrospun polyurethane prepared using radiation induced grafting |
author_facet |
Ahmad Tarmizi, Zatil Izzah Rasit Ali, Roshafima Nasef, Mohamed Mahmoud Mohamed Radzi, Afifah Mardhiah Md Akim, Abdah Eshak, Zolkapli Md Noor, Sabariah Shafie, Nur Fathin Amirah Mohd Faizo, Syazwani |
author_sort |
Ahmad Tarmizi, Zatil Izzah |
title |
Thermal and degradation analysis of electrospun polyurethane prepared using radiation induced grafting |
title_short |
Thermal and degradation analysis of electrospun polyurethane prepared using radiation induced grafting |
title_full |
Thermal and degradation analysis of electrospun polyurethane prepared using radiation induced grafting |
title_fullStr |
Thermal and degradation analysis of electrospun polyurethane prepared using radiation induced grafting |
title_full_unstemmed |
Thermal and degradation analysis of electrospun polyurethane prepared using radiation induced grafting |
title_sort |
thermal and degradation analysis of electrospun polyurethane prepared using radiation induced grafting |
publisher |
Semarak Ilmu Publishing |
publishDate |
2023 |
url |
http://psasir.upm.edu.my/id/eprint/110128/ https://semarakilmu.com.my/journals/index.php/fluid_mechanics_thermal_sciences/article/view/1520 |
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1811686049270726656 |
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13.2014675 |