Mechanistic synthesis of a sequential calcium-carboxylate-based linker (Ca-MOFs) and rapid assessment of chemical stability through XRD analysis

• Main Authors: Roslan, Muhammad Qusyairi Jori, Aris, Ahmad Zaharin, Abdul Rahman, Mohd Basyaruddin, Ngee, Lim Hong, Mohd Isa, Noorain, Ahmad Aljafree, Nurul Farhana
• Format: Article
• Published: Elsevier 2024
• Online Access: http://psasir.upm.edu.my/id/eprint/106163/; https://linkinghub.elsevier.com/retrieve/pii/S0022286024000899

Many MOFs based on various metal ions including s-, p-, d-, and f-block elements have been developed over the past decade. Despite their abundance, low cost, and non-toxicity, s-block MOFs have been explored less frequently than those based on transition metals and f-block metal ions. Sequential calcium carboxylate-based linker MOFs (Ca-MOFs) were successfully synthesized and constructed using a solvothermal system and coordination bonding. Sequential Ca-MOFs were subjected to 13 different environments to thoroughly examine their framework stability. The investigation demonstrated a calcium-carboxylate-based linker possessing superior robustness towards hydrolysis, Brønsted–Lowry acid–bases, and polarity stability from crystallite modification through the XRD spectrum before and after exposure. In this study, the Ca-H2BDC framework was found to be highly chemically stable with almost no observed crystallite modifications. The stability of sequential calcium-carboxylate-based linker MOFs reflects strong coordination bonding according to the hard soft acid base (HSAB) principle.