Understand the effect of the confinedtrifluoromethane sulfonate (OTf−) anions by the adjacent MXene nanosheets on oriented design of Zn ion storage

• 主要な著者: Liu, Xin, Du, Mingdong, Zheng, Shunri, Tan, Kar Ban, Zhao, Cuimei, Li, Junyan, Gu, Qinhua, Han, Wenjuan, Xu, Shichong, Lu, Ming, Li, Haibo, Zhang, Bingsen
• フォーマット: 論文
• 出版事項: Elsevier 2024
• オンライン･アクセス: http://psasir.upm.edu.my/id/eprint/105637/; https://linkinghub.elsevier.com/retrieve/pii/S0008622324000459

Ion pre-intercalation regulating the tunnel structure of electrode materials accelerates Zn2+ insertion kinetics to realize a high energy storage contribution of Zn-ion batteries. However, electrostatic interaction induced by the pre-intercalated cation and multivalent Zn2+ ions hinders the insertion of Zn2+/H+. In order to retain the negative interlayer surface, herein, OTf− anions were intercalated into the confined spacing by MXene via an electrochemical-driven method. Without changing the potential state of the interlayer spacings, OTf− anion induced a regulated interlayer distance, and a higher oxidation state of V based on the space occupation and the electron transfer mechanism. Consequently, the zinc ion storage capacity of V2CTx MXene increases from 125.2 to 288.7 mAh/g at 0.5 A/g. Interestingly, the negatively charged MXene surface was still intact, which presents lower diffusion barriers of the Zn2+ ions. The merits of anion pre-intercalation are highlighted and provide new insights into the ion storage function-oriented design of MXene.